文章编号:1009−444X(2023)01−0012−08CoFe2O4/BiOI磁性光催化剂的制备及其六价铬去除应用叶恒暄1,季璇1,李芷妍1,方青1,张慧青2,黄婷婷1,杨靖霞1(1.上海工程技术大学化学化工学院,上海201620;2.河南省科学院化学研究所有限公司,郑州450002)摘要:水体中的重金属六价铬离子对人体、环境均有严重影响,其含量是水体质量优劣的重要指标之一,需要对其进行严格控制.以BiOI为光催化剂,CoFe2O4(简称CFO)作为复合材料的磁性成分,合成CFO/BiOI纳米磁性光催化材料,研究不同摩尔比的CFO/BiOI对六价铬去除性能的影响.研究发现,CFO/BiOI复合材料在六价铬催化去除中,表现出比纯CFO和BiOI更好的性能.此外,CFO的引入赋予了材料磁性,可将催化材料通过磁力快速分离.关键词:磁性纳米材料;光催化;六价铬去除中图分类号:O69文献标志码:APreparationofCoFe2O4/BiOImagneticphotocatalystanditsapplicationinCr(VI)removalYEHengxuan1,JIXuan1,LIZhiyan1,FANGQing1,ZHANGHuiqing2,HUANGTingting1,YANGJingxia1(1.SchoolofChemistryandChemicalEngineering,ShanghaiUniversityofEngineeringScience,Shanghai201620,China;2.InstituteofChemistryCo.,Ltd.HenanAcademyofSciences,Zhengzhou450002,China)Abstract:Theheavymetalhexavalentchromium(Cr(VI))ioninwaterhasseriousimpactonhumanbodyandenvironment,anditsconcentrationisoneoftheimportantindicatorsofwaterquality,whichneedstobestrictlycontrolled.CFO/BiOInanometermagneticphotocatalystmaterialwassynthesizedwithBiOIasphotocatalystandCoFe2O4(CFOforshort)asmagneticcomponentofcompositematerial,andtheeffectofdifferentproportionofCFO/BiOIontheremovalperformanceofhexavalentchromiumwasstudied.ItwasfoundthattheCFO/BiOIcompositeexhibitedbettercatalyticperformancethanpureCFOandBiOIintheapplicationofhexavalentchromiumremoval.ThismaybecausedbytheconstructionofheterojunctionbetweenCFOandBiOI,whichacceleratedthechargeseparation.Inaddition,theintroductionofCFOendowedtheBiOImaterialwithmagnetism,whichallowedrapidlyseparationofthecatalystthroughmagneticforce.Keywords:magneticnano-material;photocatalysis;hexavalentchromium(Cr(VI))removal六价铬具有难降解特性,随着社会工业化水平的发展,水体中的重金属六价铬离子污染...