PesticideScienceandAdministration2023,44(1)农药研究25%吡唑醚菌酯悬浮剂在蓝莓中的残留行为及膳食风险评估朱卫芳1,黄兰淇2,张颂函2,马琳2,陈建波2,方朝阳3*(1.上海市青浦区农产品质量安全中心,上海2017002;2.上海市农业技术推广服务中心,上海201103;3.上海市松江区新浜镇农业农村服务中心,上海201600)收稿日期:2022-11-4基金项目:上海市科技兴农项目(2020-02-08-00-08-F01456).作者简介:朱卫芳,女,高级农艺师,主要从事农药残留分析及农产品安全监管方面的工作。E-mail:shqpnj@163.com。通讯作者:方朝阳,女,高级农艺师,主要从事农药残留分析及农产品安全监管方面的工作。E-mail:854311404@qq.com。ResidueandDietaryExposureandRiskAssessmentofPyraclostrobinResidueinBlueberriesZhuWeifang(ShanghaiQingpuDistrictAgriculturalProductQualityandSafetyCenter,Shanghai201700,China)HuangLanqi,ZhangSonghan,MaLin,ChenJianbo(ShanghaiAgriculturalTechnologyExten-sionandServiceCenter,Shanghai201103,China)FangZhaoyang(ShanghaiSongjiangDistrictXinbangtownAgriculturalandruralservicecenter,Shanghai201600,China)Abstract:Toassessthedietaryexposureriskofpyraclostrobinresidueinblueberries,thefinalresiduesanddeclinetrendsofpyraclostrobinusedinblueberrieswereinvestigated.Thedietaryex-posureandriskassessmentwereconductedbasedondatafromthesupervisedfieldtrial.Theblue-berriesweretreatedtwicewithpyraclostrobinatarateof150a.imL/hm2withaseven-dayinter-val.Theresultsshowedthattheaveragerecoveriesofpyraclostrobininblueberrysamplesatthefivespikedlevelsfrom0.01~1mg/kgwere92%~100%,withtherelativestandarddeviation(RSD)rangingfrom2.9%~9.4%.Thelimitofquantification(LOQs)ofpyraclostrobininblueberrieswas0.01mg/kg.Thedeclinedynamicsofpyraclostrobinfollowedfirst-orderkineticswithahalf-lifeof4.7d.Thefinalresiduelevelofpyraclostrobinatharvestrangedfrom0.11~0.29mg/kgon—74—农药研究PesticideScienceandAdministration2023,44(1)days3,5,7,10afterthelastapplication.Thechronicriskquotientofpyraclostrobinwascalcu-latedfromtheresiduetrialdata,theiracceptabledailyintake,dietaryconsumptionandbodyweightofChineseresidents...