_STP_1188-1993.pdf

STP 1188 Electrochemical Impedance:Analysis and Interpretation John R.Scully,David C.Silverman,and Martin W.Kendig,Editors ASTM Publication Code Number(PCN):04-011880-27 1916 Race Street Philadelphia,PA 19103 Copyright by ASTM Intl(all rights reserved);Tue Dec 29 00:51:18 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Library of Congress Cataloging-in-Publication Data Electrochemical impedance:analysis and interpretation/John R.Scully,David C.Silverman,and Martin W.Kendig,editors.(STP;1188)ASTM publication code number(PCN):04-011880-27.Includes bibliographical references and indexes.ISBN 0-8031-1861-9 1.Corrosion and anti-corrosives.2.Electric resistance-Data processing.3.Electrochemical analysis-Data processing.I.Scully,John R.,1958-II.Silverman,David C.,1947-III.Kendig,Martin W.IV.Series:ASTM special technical publication;1188.TA418.74.E43 1993 620.l 1223-dc20 92-42059 CIP Copyright?9 1993 AMERICAN SOCIETY FOR TESTING AND MATERIALS,Philadelphia,PA.All rights reserved.This material may not be reproduced or copied,in whole or in part,in any printed,mechanical,electronic,film,or other distribution and storage media,without the written consent of the publisher.Photocopy Rights Authorization to photocopy items for internal or personal use,or the internal or personal use of specific clients,is granted by the AMERICAN SOCIETY FOR TESTING AND MATERIALS for users registered with the Copyright Clearance Center(CCC)Transactional Reporting Service,provided that the base fee of$2.50 per copy,plus$0.50 per page is paid directly to CCC,27 Congress St.,Salem,MA 01970;(508)744-3350.For those organizations that have been granted a photocopy license by CCC,a separate system of payment has been arranged.The fee code for users of the Transactional Reporting Service is 0-8031-1861-9-93$2.50+.50.Peer Review Policy Each paper published in this volume was evaluated by three peer reviewers.The authors addressed all of the reviewers comments to the satisfaction of both the technical editor(s)and the ASTM Committee on Publications.The quality of the papers in this publication reflects not only the obvious efforts of the authors and the technical editor(s),but also the work of these peer reviewers.The ASTM Committee on Publica-tions acknowledges with appreciation their dedication and contribution to time and effort on behalf of ASTM.Printed in Fredericksburg,VA March 1993 Copyright by ASTM Intl(all rights reserved);Tue Dec 29 00:51:18 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Foreword This publication,Electrochemical Impedance:Analysis and Interpretation,contains papers presented at the symposium of the same name,held in San Diego,CA on 4-5 November 1991.The symposium was sponsored by ASTM Committee G-1 on Corrosion of Metals.John R.Scully,University of Virginia,Center for Electrochemical Science and Engineering,David C.Silverman,Monsanto,and Martin W.Kendig,Rockwell Interna-tional Science Center,presided as symposium chairmen and are editors of the resulting publication.Copyright by ASTM Intl(all rights reserved);Tue Dec 29 00:51:18 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Contents Overview MODELING AND CORROSION PROCESSES Impedance Spectra Calculated from Model Polarization Curves-u.BERTOCCI AND R.E.RICKER Discussion Specific Aspects of Impedance Measurements in Low Conductivity Media-s.CHECHRLIAN,M.KEDDAM,AND H.TAKENOUTI Analysis of EIS Data for Common Corrosion Processes-F.MANSFELD,H.SHIH,H.GREENE,AND C.H.TSAI Analyzing Simulated Electrochemical Impedance Spectroscopy Results by the Systematic Permutation of Data Points-P.R.ROBERGE The Effect of Parasitic Conduction Pathways on EIS Measurements in Low Conductivity Media-K.C.STEWART,D.G.KOLMAN,AND S.R.TAYLOR The Characterization of the Coarsening of Dealloyed Layers by EIS and Its Correlation with Stress-Corrosion Cracking-R.G.KELLY,A.J.YOUNG,AND R.C.NEWMAN 9 22 23 37 54 73 94 APPLICATIONS OF KRAMERS-KRONIG TRANSFORMATIONS Application of the Kramers-Kroulg Relations in Electrochemical Impedance SpeetroscopymP.AGARWAL,M.E.ORAZEM,AND L.H.GARCIA-RUBIO Kramers-Kronig Transformation in Relation to the Interface Regulating Devicem C.GABRIELLI,M.KEDDAM,AND H.TAKENOUTI Validation of Experimental Data from High Impedance Systems Using the Kramers-Kronig TransformsmB.J.DOUGHERTY AND S.I.SMEDLEY 115 140 154 CORROSION AND INHIBITION The Impedance Response of Film-Covered Metals-s.TURGOOSE AND R.A.COTTIS Corrosion Prediction from Circuit Models Application to Evaluation of Corrosion InhibitorsbD.c.SILVERMAN 173 192 Copyright by ASTM Intl(all rights reserved);Tue Dec 29 00:51:18 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No furthe