_STP_1119-1992.pdf

STP 1119 Analysis of Paints and Related Materials:Current Techniques for Solving Coatings Problems William C.Golton,editor ASTM Publication Code Number(PCN)04-011190-14 sTM 1916 Race Street Philadelphia,PA 19103 Copyright by ASTM Intl(all rights reserved);Thu Dec 31 13:03:03 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Library of Congress Cataloging-in-Publication Data Analysis of paints and related materials:current techniques for solving coatings problems.p.cm.-(ASTM special technical publication;1119)Includes bibliographical references and index.ISBN 0-8031-1465-6 1.Paint-Analysis.I.Series.TP936.5.A527 1992 667.6-dc20 92-22563 CIP Copyright o 1992 AMERICAN SOCIETY FOR TESTING AND MATERIALS,Phil-adelphia,PA.All rights reserved.This material may not be reproduced or copied,in whole or in part,in any printed,mechanical,electronic,film,or other distribution and storage media,without the written consent of the publisher.Photocopy Rights Authorization to photocopy items for internal or personal use,or the internal or personal use of specific clients,is granted by the AMERICAN SOCIETY FOR TESTING AND MATERIALS for users registered with the Copyright Clearance Center(CCC)Transactional Reporting Service,provided that the base fee of$2.50 per copy,plus$0.50 per page is paid directly to CCC,27 Congress St.,Salem,MA 01970;(508)744-3350.For those organizations that have been granted a photocopy license by CCC,a separate system of payment has been arranged.The fee code for users of the Transactional Reporting Service is 0-8031-1465-6/92$2.50+.50.Peer Review Policy Each paper published in this volume was evaluated by three peer reviewers.The authors addressed all of the reviewers comments to the satisfaction of both the technical editor(s)and the ASTM Committee on Publications.The quality of the papers in this publication reflects not only the obvious efforts of the authors and the technical editor(s),but also the work of these peer reviewers.The ASTM Committee on Publications acknowledges with appreciation their dedication and contribution to time and effort on behalf of ASTM.Printed in Baltimore,MD August,1992 Copyright by ASTM Intl(all rights reserved);Thu Dec 31 13:03:03 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Foreword This publication,Analysis of Paints and Related Materials:Current Techniques for Solving Coatings Problems,contains papers presented at the symposium of the same name held in Pittsburgh,Pennsylvania on 13-14 May 1990.The symposium was sponsored by ASTM Committee D-I on Paint and Related Materials and its Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials.The symposium chairman was William C.Golton,E.I.duPont de Nemours&Company,Inc.,Philadelphia.He also served as editor of this publication.Copyright by ASTM Intl(all rights reserved);Thu Dec 31 13:03:03 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Contents Overview vii ANALYSIS AND CHARACTERIZATION OF WHOLE PAINT Modern Analytical Techniques for Coating and Coating Materials-ULRICH SCHERNAU,BERNHARD HUESER,AND KARIN WEBER Mass Spectrometric Techniques for Coatings Characterization-WILLIAM J.SIMONSICK,JR.22 ANALYSIS AND CHARACTERIZATION OF PAINT COMPONENTS HPLC Analysis for Epoxy Coatings Resins-DAVID P.SHEIH AND DONALD E.BENTON 41 Application of Size Exclusion Chromatography to Polymers and Coatings-CHENG-YIH KUO AND THEODORE PROVDER 57 X-Ray Techniques for Coatings Analysis-A.MONROE SNIDER,JR.82 Practical Applications of Gas Chromatography in the Paint and Coatings Industry-FRANCIS X.YOUNG 105 CURE CHARACTERIZATION,DURABILITY,AND COATING PROBLEMS Applications of FTIR to Paint Analysis-JACK H.HARTSHORN 127 Chemical Characterization of Cross-Linked Polyurethane Films-L.G.J.VAN DER VEN,G.D.B.VAN HOUWELINGEN,AND R.R.LAMPING 148 Principles and Applications of Photoelectron and Ion Spectroscopy for the Analysis of Polymer Surfaces-JOSEPH A.GARDELLA,JR.157 PAINT FAILURE AND DEFECTS FTIR Techniques for the Analysis of Coating Problems:Solid Sampling AccessorieS-ANNE M.MILLON AND JAMES M.JULIAN Failure Analysis of Applied CoatingS-KENNETH a.TATOR AND DWIGHT G.WELDON 173 196 Copyright by ASTM Intl(all rights reserved);Thu Dec 31 13:03:03 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Overview The purpose of the two-day symposium was to present and discuss the latest techniques and instruments used to analyze and characterize paints,coatings,and related materials.The symposium was sponsored by ASTM standards-writing Committee D-1 on Paint and Related Coatings and Materials and its Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materi