ASTM_DS53-1974.pdf

LIST OF FLUORESCENT WHITENING AGENTS FOR THE SOAP AND DETERGENT INDUSTRY Report of the Task Group on Fluorescent Whitening Agents,D12.15.05,of ASTM Committee D-12 on Soaps and Other Detergents ASTM Data Series DS 53 List price$3.00 05-053000-15#AMERICAN SOCIETY FOR TESTING AND MATERIALS 1916 Race Street,Philadelphia,Pa.19103 5BY AMERICAN SOCIETY FOR TESTING AND MATERIALS 1974 Library of Congress Catalog Card Number:74-75394 NOTE The Society is not responsible,as a body,for the statements and opinions advanced in this publication.Printed in West Point,Pa.April 1974 Contents Introduction 1 Key to Letter Designation of Chemical Structures 2 ASTM List of Fluorescent Whitening Agents 3 C Type 3 DASC Type 3 NTS Type 5 P Type 5 SNO Type 6 Names and Addresses of FWA Suppliers 7 Related ASTM Publications Bibliographical Abstracts on Evaluation of Fluorescent Whitening Agents 1929-1968,STP 507(1972),$3.25(04-507000-15)Introduction By far,the largest single consumer of Fluorescent Whitening Agents(FWAs)is the soap and detergent industry.In the past,the identification of these products in test methods,publications,customs declarations,etc.has been primarily limited to individual suppliers trade names which often create confusion and ambiguity.Although several of the products are in-cluded in the Colour Index,this compilation is incomplete and,in some instances,inaccurate.ASTM Task Group on Fluorescent Whitening Agents,D12.15.05,of Committee D-12 on Soaps and Other Detergents,is currently developing ASTM test procedures for Fluorescent Whitening Agents and,in connection with these efforts,has compiled this listing of FWAs used commercially in substantial amounts in soap and detergent formulations.The identification of the chemical structure of each FWA by a unique set of letters and num-bers is the most important and useful feature of this publication.The letter-number designation for each FWA will be used in the ASTM test methods being developed by ASTM Task Group D12.15.05,and it is expected that the designations will also be valuable to other organizations and committees,individual authors,etc.involved in the FWA field.Included in the listing are the brand names and the names and addresses of the suppliers of FWAs who have participated in this project by making the necessary disclosures.ASTM Task Group D12.15.05 would like to ex-press its appreciation to those suppliers for their cooperation.DS53-EB/Apr.1974Copyright 1974 by ASTM International www.astm.org Key to Letter Designation of Chemical Structures C COUMARIN R3 R2 I rRi c=0 vv DASC DIAMINOSTILBENEDISULFONIC ACID-CYANURIC CHLORIDE Ri.C=N 7 X X N C -Yi-f X X/X=/C-N I-+/S03 R R3 N-C J-c CH-CH/w u r+S03 R/X /N N -C R+H+,Na+,K+,etc.NTS NAPHTHOTRIAZOLYLSTILBENE N R2 N U Re P PYRAZOLINE N/R,-C N -R2 I I CHJJ CH2 SNO STYRYLNAPHTHOXAZOLE y /CH Ri/VX CH -C II !x Ay Designation C-l Chemical structure ASTM List of Fluorescent Whitening Agents CType CH3 CHc CH=/X NA/CH 0 Chemical Abstracts name:7-Dimethylamino-4-methylcoumarin Suppliers and brand names American Cyanamid Company,Calcofluor White LD The Hilton-Davis Chemical Co.,Hiltamine Artie White N Designation C-2 Chemical structure CH3 C2H5 V XCT N/C2H5 X/0 C =0 Chemical Abstracts name:7-Diethylamino-4-methylcoumarin Suppliers and brand names American Cyanamid Company,Calcofluor White SD Ciba-Geigy Corporation,Uvitex SWN Cone The Hilton-Davis Chemical Co.,Hiltamine Arctic White SOL DASC Type Designation DASC-1 Chemical structure.sA _/N N /C -N H i N X/N 5/.yx l n.+r.+S03 R SO3 R XX _/N -C y x C N /N=C H x=/Chemical Abstracts name:4,4-Bis(4,6-dianilino-s-triazin-2-yl)amino-2,2-stilbenedisulfonic Acid Suppliers and brand names GAF Corporation,BlancophorCN Verona,Div.of Baychem Corp.,Phorwite HZPA 766 esignation DASC-2 Chemical structure C/-N X N c HOCHpCHp C /=N N/HOCH2CH2 N CH2CH2OH Chemical Abstracts name:4,4-Bis 4-anilino-6-bis(2-hydroxyethyl)amino-s-triazin-2-yl amino-2,2-stilbenedisulfonic Acid Suppliers and brand names American Cyanamid Company,Calcofluor White M2R New American Cyanamid Company,Calcofluor White CG Cone,(free sulfonic acid form)Ciba-Geigy Corporation,Tinopal UNPA Ciba-Geigy Corporation,Tinopal UNPS(disodium salt)GAF Corporation,BlancophorRG The Hilton-Davis Chemical Co.,Hiltamine Artie White CWD Verona,Div.of Baychem Corp.,Phorwite BBH Pure 766 Designation DASC-3 Chemical structure C -N N -C N c -N_/-CH=CH-_/-c N /1 r /CH2-CH2 C =N -+-+N =C CH2-CH2 y y SO3 R SO3 R /ON NO /./CH2-CH2 CH2-CH2 Chemical Abstracts name:4,4-Bis(4-anilino-6-morpholino-s-triazin-2-yl)amino-2,2-stilbenedisulfonic Acid Suppliers and brand names American Cyanamid Company,Calcofluor White RC Cone.American Cyanamid Company,Calcofluor White RCX Super Cone.Ciba-Geigy Corporation,Tinopal AMS Ciba-Geigy Corporation,Tinopal AMS Pure GAF Corporation,BIancophorDS The Hilton-Davis Chemical Co.,Hiltamine Artie White DML Verona,Div.of Baychem Corp.,Phorwite MBBH 766 Designation DASC-4 Chemical structure C -N N -C /j r-N/CH CN I-+l_+NC CH3