ASTM_DS53A-1974.pdf

LIST OF FLUORESCENT WHITENING AGENTS FOR THE SOAP AND DETERGENT INDUSTRY Report of the Task Group on Fluorescent Whitening Agents,D12.15.05,of ASTM Committee D-12 on Soaps and Other Detergents ASTM Data Series DS 53 A List price$3.00 05-053010-15 b AMERICAN SOCIETY FOR TESTING AND MATERIALS 1916 Race Street,Philadelphia,Pa.19103 by AMERICAN SOCIETY FOR TESTING AND MATERIALS 1974 Library of Congress Catalog Card Number:76-9470 NOTE The Society is not responsible,as a body,for the statements and opinions advanced in this publication.Printed in Philadelphia,Pa.July 1976 Contents Introduction 1 Key to Letter Designation of Chemical Structures 2 ASTM List of Fluorescent Whitening Agents 3 C Type 3 DASC Type 3 DSBP Type 5 NTS Type 6 P Type 6 Names and Addresses of FWA Suppliers 7 Related ASTM Publications Bibliographical Abstracts on Evaluation of Fluorescent Whitening Agents 1929-1968,STP 507(1972),$3.25(04-507000-15)Introduction By far,the largest single consumer of Fluorescent Whitening Agents(FWAs)is the soap and detergent industry.In the past,the identification of these products in test methods,publications,customs declarations,etc.has been primarily limited to individual suppliers trade names which often create confusion and ambiguity.Although several of the products are in-cluded in the Colour Index,this compilation is incomplete and,in some instances,inaccurate.ASTM Task Group on Fluorescent Whitening Agents,D12.15.05,of Committee D-12 on Soaps and Other Detergents,is currently developing ASTM test procedures for Fluorescent Whitening Agents and,in connection with these efforts,has compiled this listing of FWAs used commercially in substantial amounts in soap and detergent formulations.The identification of the chemical structure of each FWA by a unique set of letters and num-bers is the most important and useful feature of this publication.The letter-number designation for each FWA will be used in the ASTM test methods being developed by ASTM Task Group D12.15.05,and it is expected that the designations will also be valuable to other organizations and committees,individual authors,etc.involved in the FWA field.Included in the listing are the brand names and the names and addresses of the suppliers of FWAs who have participated in this project by making the necessary disclosures.ASTM Task Group D12.15.05 would like to ex-press its appreciation to those suppliers for their cooperation.DS53A-EB/Jul.1976Copyright 1976 by ASTM International www.astm.org Key to Letter Designation of Chemical Structures C COUMARIN AALR R3 I C =0 DASC DIAMINOSTILBENEDISULFONIC ACID-CYANURIC CHLORIDE C=N N C -Nf X X/=/C -N I-+/S03 R R3 N *C vS-cx CH-CH/w r+S03 R/X /N N -C R+H+,Na+,K+,etc.DSBP DISTYRYLBIPHENYL -CH=CH.CH=CH R2 R3 NTS NAPHTHOTRIAZOLYLSTILBENE N X=CHCH-X=,/KN P PYRAZOLINE N R,-C CH=N -R2 I CH2 Designation C-l Chemical structure ASTM List of Fluorescent Whitening Agents CType CH3 CH=/X N_xA/CH CH3 Chemical Abstracts name:7-Dimethylamino-4-methylcoumarin Suppliers and brand names American Cyanamid Company,Calcofluor White LD The Hilton-Davis Chemical Co.,Hiltamine Artie White N Designation C-2 Chemical structure CH3 CSH5/XCH N/C2H5 V /0 c=0 Chemical Abstracts name:7-Diethylamino-4-methylcoumarin Suppliers and brand names American Cyanamid Company,Calcofluor White SD Ciba-Geigy Corporation,Uvitex SWN Cone Sandoz Inc.,Colors and Chemicals Division,Aclarat 8678 The Hilton-Davis Chemical Co.,Hiltamine Arctic White SOL DASC Type Designation DASC-1 Chemical structure (N/H 1 N-.X I/N -C N-/-CHH-Ny-N -C N=i r /I -+I -+N=c A S03 R S03 R Chemical Abstracts name:4,4-Bis(4,6-dianilino-s-triazin-2-yl)amino-2,2-stilbenedisulfonic Acid X Suppliers and brand names GAF Corporation,BlancophorCN Designation DASC-2 Chemical structure C/-N X N/HOCHpCHp C=N N/HOCH2CH2/=/N CHgCIfeOH Chemical Abstracts name:4,4-Bis 4-anilino-6-bis(2-hydroxyethyl)amino-s-triazin-2-ylamino-2,2-stilbenedisulfonic Acid Suppliers and brand names American Cyanamid Company,Calcofluor White M2R New American Cyanamid Company,Calcofluor White CG Cone,(free sulfonic acid form)Ciba-Geigy Corporation,Tinopal UNPA Ciba-Geigy Corporation,Tinopal UNPS(disodium salt)GAF Corporation,BlancophorRG The Hilton-Davis Chemical Co.,Hiltamine Arctic White CWD Verona Dyestuff Div.Mobay Chemical Corp.,Phorwite BBH Pure 766 Designation DASC-3 Chemical structure X H N CH-CH/C/N C/-N X c/=N-*/_CH=CH-/-*-i-+r.+S03 R S03 R N C N-C N/C CHp-CHp /N N 0 /CH2CHg CHg CH2 Chemical Abstracts name:4,4-Bis(4-anilino-6-morpholino-s-triazin-2-yl)amino-2,2-stilbenedisulfonic Acid Suppliers and brand names American Cyanamid Company,Calcofluor White RCX Super Cone.Ciba-Geigy Corporation,Tinopal AMS Ciba-Geigy Corporation,Tinopal AMS Pure GAF Corporation,BlancophorDS The Hilton-Davis Chemical Co.,Hiltamine Arctic White DML The Hilton-Davis Chemical Co.,Hiltamine Arctic White DML Ex.Cone.The Hilton-Davis Chemical Co.,Hiltamine Arctic White MSO Verona Dyestuff Div.Mobay Chemical Corp.,Phorwite MBBH 766 n.+r_