ASTM_D_2071_-_87_1998.pdf

Designation:D 2071 87(Reapproved 1998)Standard Test Methods forFatty Nitrogen Products1This standard is issued under the fixed designation D 2071;the number immediately following the designation indicates the year oforiginal adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.Asuperscript epsilon(e)indicates an editorial change since the last revision or reapproval.These test methods were prepared jointly by ASTM and the American Oil Chemists Society.1.Scope1.1 These test methods cover the testing of fatty nitrogenproducts.They specify the use of otherASTM methods that arepublished separately.The test methods included are listed inTable 1.1.2 The test methods cover the following compounds:1.2.1 Fatty AminesFatty primary amines,difatty second-ary amines,trifatty tertiary amines.1.2.2 Fatty Quaternary Ammonium ChlorideTrimethylfatty quaternary ammonium chloride,dimethyl difatty quater-nary ammonium chloride.1.2.3 Fatty AmidoaminesReaction products of fatty acidswith an excess of polyamines.1.2.4 Fatty DiaminesN-fatty-1,3-propylene diamines.1.3 This standard does not purport to address all of thesafety concerns,if any,associated with its use.It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2.Referenced Documents2.1 ASTM Standards:D 56 Test Method for Flash Point by Tag Closed Tester2D 88 Test Method for Saybolt Viscosity3D 92 Test Method for Flash and Fire Points by ClevelandOpen Cup2D 93 Test Methods for Flash Point by Pensky-MartensClosed Tester2D 1209 Test Method for Color of Clear Liquids(Platinum-Cobalt Scale)4D 1310 Test Method for Flash Point and Fire Points ofLiquids by Tag Open-Cup Apparatus5D 1466 Test Method for Sampling Liquid Oils and FattyAcids Commonly Used in Paints,Varnishes,and RelatedMaterials6D 1544 Test Method for Color of Transparent Liquids(Gardner Color Scale)5D 2072 Test Method for Water in Fatty Nitrogen Com-pounds6D 2073 Test Methods for Total,Primary,Secondary,andTertiaryAmine Values of FattyAmines,Amidoamines,andDiamines by Referee Potentiometric Method6D 2074 Test Methods for Total,Primary,Secondary,andTertiary Amine Values of Fatty Amines by AlternativeIndicator Method61These test methods are under the jurisdiction ofASTM Committee D-1 on Paintand Related Coatings,Materials,and Applications,and are the direct responsibilityof Subcommittee D01.32 on Drying Oils.Current edition approved June 26,1987.Published August 1987.Originallypublished as D 2071 62 T.Last previous edition D 2071 75(1980)e1.2Annual Book of ASTM Standards,Vol 05.01.3Annual Book of ASTM Standards,Vol 04.04.4Annual Book of ASTM Standards,Vol 06.04.5Annual Book of ASTM Standards,Vol 06.01.6Annual Book of ASTM Standards,Vol 06.03.TABLE 1 List of Test MethodsTest MethodSectionsASTMDesignationof Test MethodDefinition4All Fatty Nitrogen Products:Sampling5D 1466Color by the Gardner Method6D 1544Color by the APHA Method7D 1209Water by the Karl Fischer Method8D 2072Fatty Amines:Amine values9D 2073D 2074Iodine value10D 2075Percent non-amine11D 2082Primary,secondary,tertiary amines12D 2083Fatty Quaternary Ammonium Chlorides:Acid value and amine value13D 2076Ash14D 2077Flash point15D 56D 88D 92D 93D 1310D 3278Iodine value16D 2078Nonvolatile matter17D 2079Average molecular weight18D 2080pH19D 2081Fatty Amidoamines:Amine values20D 2073Iodine value21D 2075Fatty Diamines:Amine values22D 2073Iodine values23D 2075Percent non-amines24D 20821AMERICAN SOCIETY FOR TESTING AND MATERIALS100 Barr Harbor Dr.,West Conshohocken,PA 19428Reprinted from the Annual Book of ASTM Standards.Copyright ASTMD 2075 Test Method for Iodine Value of Fatty Amines,Amidoamines,and Diamines6D 2076 Test Methods for Acid Value and Amine Value ofFatty Quaternary Ammonium Chlorides6D 2077 Test Method for Ash in Fatty Quaternary Ammo-nium Chlorides6D 2078 Test Method for Iodine Value of Fatty QuaternaryAmmonium Chlorides6D 2079 Test Method for Nonvolatile Matter(Solids)inFatty Quaternary Ammonium Chlorides6D 2080 Test Method forAverage Molecular Weight of FattyQuaternary Ammonium Chlorides6D 2081 Test Method for pH of Fatty Quaternary Ammo-nium Chlorides6D 2082 Test Method for Percent of Non-amines in FattyNitrogen Compounds6D 2083 Test Method for Calculation of Percent of Primary,Secondary,and Tertiary Amines in Fatty Amines6D 3278 Test Methods for Flash Point of Liquids by SmallScale Closed-Cup Apparatus53.Terminology3.1 Definition:3.1.1 fatty nitrogen productsnitrogen containing com-pounds derived from vegetable and animal fatty acids.3.1.1.1 DiscussionVegetable and animal fatty acids in-clude coconut,cotton,soya,tallow and tall oil fatty acids,fattyacid fractions thereof,and hydrogenated fatty acids.4.Significance and Use4.1 These test methods list the methods used to test fattyamines,fatty quaternary ammonium chlorides,fatty amidoam-ines and fatty diamines.The