ASTM_D_1153_-_22.pdf

Designation:D115322Standard Specification forMethyl Isobutyl Ketone1,2This standard is issued under the fixed designation D1153;the number immediately following the designation indicates the year oforiginal adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.Asuperscript epsilon()indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S.Department of Defense.1.Scope1.1 This specification covers methyl isobutyl ketone(99.0%grade).1.2 For specific hazard information and guidance,see thesuppliers Material Safety Data Sheet for materials listed in thisspecification.1.3 The following applies to all specified limits in thisstandard;for purposes of determining conformance with thisstandard,an observed value or a calculated value shall berounded off“to the nearest unit”in the last right-hand digitused in expressing the specification limit,in accordance withthe rounding-off method of Practice E29.1.4 The values stated in SI units are to be regarded asstandard.No other units of measurement are included in thisstandard.1.5 This standard does not purport to address all of thesafety concerns,if any,associated with its use.It is theresponsibility of the user of this standard to establish appro-priate safety,health,and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade(TBT)Committee.2.Referenced Documents2.1 ASTM Standards:3D268 Guide for Sampling and Testing Volatile Solvents andChemical Intermediates for Use in Paint and RelatedCoatings and Material(Withdrawn 2021)4D1078 Test Method for Distillation Range of Volatile Or-ganic LiquidsD1209 Test Method for Color of Clear Liquids(Platinum-Cobalt Scale)D1296 Test Method for Odor of Volatile Solvents andDiluents(Withdrawn 2021)4D1353 Test Method for Nonvolatile Matter in Volatile Sol-vents for Use in Paint,Varnish,Lacquer,and RelatedProductsD1364 Test Method for Water in Volatile Solvents(KarlFischer Reagent Titration Method)(Withdrawn 2021)4D1476 Test Method for Heptane Miscibility of LacquerSolvents(Withdrawn 2021)4D1613 Test Method for Acidity in Volatile Solvents andChemical Intermediates Used in Paint,Varnish,Lacquer,and Related ProductsD3329 Test Method for Purity of Methyl Isobutyl Ketone byGas ChromatographyD4052 Test Method for Density,Relative Density,and APIGravity of Liquids by Digital Density MeterD5386 Test Method for Color of Liquids Using TristimulusColorimetryE1 Specification for ASTM Liquid-in-Glass ThermometersE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE300 Practice for Sampling Industrial Chemicals2.2 U.S.Federal Specification:5PPP-C-2020 Chemicals,Liquid,Dry,and Paste:Packagingof3.Properties3.1 Methyl isobutyl ketone(99.0%grade)shall conform tothe following requirements:1This specification is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings,Materials,and Applications and is the direct responsibility ofSubcommittee D01.35 on Solvents,Plasticizers,and Chemical Intermediates.Current edition approved Jan.1,2022.Published January 2022.Originallyapproved in 1951.Last previous edition approved in 2012 as D1153 12 which waswithdrawn January 2021 and reinstated in January 2022.DOI:10.1520/D1153-22.2This compound is also known under the name of 2-methyl-4-pentanone.3For referenced ASTM standards,visit the ASTM website,www.astm.org,orcontact ASTM Customer Service at serviceastm.org.For Annual Book of ASTMStandards volume information,refer to the standards Document Summary page onthe ASTM website.4The last approved version of this historical standard is referenced onwww.astm.org.5Available from Standardization Documents Order Desk,DODSSP,Bldg.4,SectionD,700RobbinsAve.,Philadelphia,PA19111-5098,http:/dodssp.daps.dla.mil.Copyright ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959.United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade(TBT)Committee.1?Methyl isobutyl ketone wt%,min99.0Apparent specific gravity:20/20 C0.800 to 0.803or25/25 C0.796 to 0.799Color,Pt-Co units,maxA15Distillation,CInitial boiling point,min114.0Dry point,max117.0Nonvolatile matter,mg/100 mL,max5OdorBnonresidualWater,wt%,maxC0.1Acidity(free acid as acetic acid),wt%,max0.01Methyl isobutyl carbinol,wt%,max0.3AInstrumental Pt-Co color determined