ASTM_D_3246_-_15_rus.pdf

D 3246-15 STANDARD TEST METHOD FOR SULFUR IN PETROLEUM GAS BY OXIDATIVE MICROCULONOMETRY 2016 ():2826-15/ASTM :29.01.2016 -,.9,-49,-1,119991.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D 3246-15 1 D 3246-15 1 D 3246;,.().1.*1.1 1,5 100/(),.1 .1.2,.1.3 ,.1 ASTM D02 ,D02.03 .1 2015.2015.1973.2014.D3246-14.DOI:10.1520/D3246-15.ASTM D 3246-15 2 ,.2.2.1 ASTM:2 D 1265 (LP),D 1193 D 3120 D 6299 F 307 2.2 :G-4 G-4-1 3 3.3.1 ,800,80%20%(,.).,-2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.3 ,1235 Jefferson Davis Hwy.,Arlington,VA 22202.ASTM D 3246-15 3,.,.,.3.2 :I3+SO2+H2O SO3+3I+2H+(1)-,:3I I3+2e (2)3.3 (),.3.4 ,.4 4.1 ,.,.4.2 .ASTM D 3246-15 4 5.5.1 ,1,0%.5.2 (,Ni,V,Pb .),500/.2 ,.6.4,5 6.1 ,:,.6.1.1 :4,6.1 6.5.,Tekmar-Dohrmann,7143 E,Kemper Rd.,Cincinnati,OH 524549.Preprints Division of Petroleum Chemistry,American Chemistry,Americal Chemical Society,Vol 1,No.3,Sept.7-12,1969,p.B232 Determination of Sulfur,Nitrogen and Chlorine in Petroleum by Microcoulometry,by Harry V.Drushel.5 ,Tekmar-Dohrmann.,-ASTM International.1,.ASTM D 3246-15 5 700 1000 ()800 6.2 ,.,.6.3 ,-,-,.-.-.,.(,.)6.4,/,.ASTM D 3246-15 6 6.5 ,0,1/25 12 25/.,.6.6 10,1 10 75,24 .3 ,(0,1 0,2/).6.7 ,5 3 .25-28.6.8 ,.7 7.1 .,.6 ,.7.2 ,6 Reagent Chemicals,American Chemical Society Specifications,Am.Chemical Soc.,Washington,DC.,.Annual Standards for Laboratory Chemicals,BDH Ltd.,Poole,Dorset,U.K.,and the United States Pharmacopeia,and National Formulary,U.S.Pharmacopeial Convention,Inc.,(USPC),Rockville,MD.ASTM D 3246-15 7.D 1193 .4 ,.7.3 (.1,05)(3).(.1.1)7.4,(),-.99,995%(.1.2.)7.5 0,5 (KI)0,6 (NaN3)500 ,5 (3)1000.5 .7.6 -.7.7 (I2),20 ,.(.1.3.)7.8 (2,2,4-),.(,.1.4.)6 ,.80 (176 F),(2,2,4-)99,3 (211 F)287,5 (549,5 F).7.9-(3222)2S.7.10,()6 -.(.1.5.)ASTM D 3246-15 8 7.11 (KI),.7.12 (NaN3),.(.,.)7.13,(30/)10 (7.14)100-.7 ,.7.14,(300 (/)0,5000 -500-.S,/=)(102187,06(3)7.15(),.10.7.16()(QC),.QC 11.ASTM D 3246-15 9 8.8.1 ,D 1265 F 307.8.2 -.9.9.1 -.9.2 .1/8 1/4 (3,2 6,4).9.3 .9.4 1 (25).9.5 .(),.(,ASTM D 3246-15 10).1.2 .9.5.1 .9.6 ,.1.1.-(),3/160 -(Ar,He,N),3/40 ,700 800 800 :,160 (200)10.10.1 ,.7.13,7.14 .10.2 (9.5).8 80%20%.10.3 .80%.10.3.1 8 ,1,.,ASTM D 3246-15 11 ,1-,.10.3.2 (),.,0,01.10.4 (),0,1 0,2/.,(/),0,1 0,2/.10.5 .9 SO2.SO3,.-,.75%.,.,75-90%.10.6%,.(1)0,1/0,5/:,%=(A 1,99)/(R S0 VL/1000)100(4):-,2,ASTM D 3246-15 12 R-,S0-,/,VL-,.10.6.1 :,%=(1,99 10-3)/(R S0 VL/1000)100(5):-100 .1.10.6.2 :,%=100BA()(6):-,/,-,/.10 .D 3120.10.6.3 ,.10.7 ,SO2 75%,.,.10.8 ,F,S/2,:F=(S0 VL/1000)/A(7)ASTM D 3246-15 13 11.(QA)11.1().,.11.2()(QC)QC.(.7.16).11.2.1 QC/QA ,.11.2.2 ,2 QC/QA.12.12.1 ,(;.1.7).,.,.12.2 ,.(.1.8.)12.3 .ASTM D 3246-15 14,5 3.12.4 .5,0 3 ,15.,10.2 10.7.12.5 .12.6 ,.13.13.1 (ppm):,/=(F)/W(8):-,(),(),W-,F-,S/2.:22410760)273(273CMPVWg(9):Vg-,3 -,.-,/,-,.ASTM D 3246-15 15 23 760 .W=Vg 0,001154(10):W=VL/1000 d(11):VL-,d-,/.13.2 ,(/).14.14.1 0,1/,D 3246.15.15.1 :15.1.1 ,:0 10/0,4/ASTM D 3246-15 16 15.1.2 ,:0 10/5/15.2 ,.16.16.1;,()1.1.1 1.1.1 .,.1.2 :,1.2.1 .,.ASTM D 3246-15 17 .,.,.,.,().-.1.3 1.3.1 .,.1.4 1.4.1 .,.ASTM D 3246-15 18 .,.1.5 1.5.1 .,.,.,.,.,.ASTM D 3246-15 19 ,.,.-.G-4 G-4.1 .1.6 1.6.1 .,.,.1.7 1.7.1 ().,.,.ASTM D 3246-15 20 .,.1.8 1.8.1 ,.,.-.()1.,13.1 1.1 ,.1.1 .1.2 .1.2.ASTM D 3246-15 21 .1.1 .1.2 1.3 :1.3.1 ,-(),(I3 3I+H+).(-),Q.1.3.2 ,i,(),(),Q(),ASTM D 3246-15 22 ;.Q=it.,Q/F,F ,95 500 .1.3.3,:=,=16FCCQ(1.1),fR96500101610602B 0,1A S632 (1.2):2-,0,1/-,2/-,60/-,10-3/-.16/-,106/-,R()-,V/R=I()21,02(1.3)1060cA3RQ(1.4)F=96 500 C/-8(-)ASTM D 3246-15 23 /-,f-(S),().fR9650010161012AS 63-(1.5)fR96500 10161012AS 6-3(1.6)S=(A1,99)/(Rf)(1.7)ppm=/,10,1,99AS/3fR(1.8)101,99AS/3fR(1.9)=/S=(A1,99)/(RF,)(1.10)1.3.4 1.7 .,.,(.)=10-3 1.=1000.10-3 5,:S=(1,99103)/(Rf)(1.11)fR,1,99 S/(1.12)ASTM D 3246-15 24 S=(1,99 10-3).(R ,f)1.1 =100 .2.2.1 ()QC.2.2 ,QC.D 6299 MNL77.2.3 QC ,.,QC.D 6299 MNL77.,().,.2.4 QC ,.QC .QC ,.,QC .QC ASTM,.D 6299 MNL77.7 ASTM MNL 7,Mannual of Presentation of Data Control Chart Analysis,6th ed.,Section 3:,ASTM International,W.Conshohocken,PA.ASTM D 3246-15 25 2.5,QC,.QC ,.2.6.D 6299 MNL77 QC .D02.03 (D 3246-14),.(1 2015.)(1).13.2,.D02.03 (D 3246-11),.(1 2014.)(1)10.6.3 13.2.ASTM D 3246-15 26 ASTM Interna