ASTM_D_4462_-_02_2019.pdf

Designation:D446202(Reapproved 2019)Standard Specification forZinc Hydroxy Phosphite Pigment1This standard is issued under the fixed designation D4462;the number immediately following the designation indicates the year oforiginal adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.Asuperscript epsilon()indicates an editorial change since the last revision or reapproval.1.Scope1.1 This specification covers a zinc hydroxy phosphitepigmenthavingthegeneralformulaZnHPO3ZnO2Zn(OH)2.1.2 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade(TBT)Committee.2.Referenced Documents2.1 ASTM Standards:2D185 Test Methods for Coarse Particles in PigmentsD280 Test Methods for Hygroscopic Moisture(and OtherMatter Volatile Under the Test Conditions)in PigmentsD281 Test Method for Oil Absorption of Pigments bySpatula Rub-outD4450 Test Method forAnalysis of Zinc Hydroxy PhosphitePigment3.Composition and Properties3.1 The pigment shall consist of zinc hydroxy phosphite andshall conform to the requirements in Table 1.3.2 The mass color of the dry pigment is white.The shadeand tinting strength,when specified,shall be within mutuallyagreed upon limits of a reference sample acceptable by thepurchaser and the seller as tested in an agreed test procedure.4.Sampling4.1 Two samples shall be taken at random from differentpackages from each lot,batch,days pack,or other unit ofproduction in a shipment.When no markings distinguishingbetween units of production appear,samples shall be takenfrom different packages,in the ratio of two samples for each10 000 lb(4545 kg),except that for shipments of less than10 000 lb two samples shall be taken.At the option of thepurchaser,the samples may be tested separately or afterblending in equal quantities the samples from the sameproduction unit to form a composite sample.5.Test Methods5.1 Tests shall be conducted in accordance with the follow-ingASTM test methods.Test procedures not covered byASTMtest methods shall be mutually agreed upon between thepurchaser and the seller.5.2 Chemical AnalysisTest Method D4450.5.3 Moisture LossDetermine the hygroscopic moistureloss by Method A of Test Methods D280.5.4 Oil AbsorptionTest Method D281.5.5 Sieve ResidueDetermine the residue on a No.325sieve in accordance with the Procedure for Insoluble DryPigments of Test Methods D185.6.Keywords6.1 phosphorous acid;pigment;zinc;zinc hydroxy phos-phite;zinc oxide1This specification is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings,Materials,and Applications and is the direct responsibility ofSubcommittee D01.31 on Pigment Specifications.Current edition approved Oct.1,2019.Published October 2019.Originallyapproved in 1985.Last previous edition approved in 2012 as D4462 02(2012).DOI:10.1520/D4462-02R19.2For referenced ASTM standards,visit the ASTM website,www.astm.org,orcontact ASTM Customer Service at serviceastm.org.For Annual Book of ASTMStandards volume information,refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959.United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade(TBT)Committee.1 ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard.Users of this standard are expressly advised that determination of the validity of any such patent rights,and the riskof infringement of such rights,are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised,either reapproved or withdrawn.Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters.Your comments will receive careful consideration at a meeting of theresponsible technical committee,which you may attend.If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards,at the address shown below.This standard is copyrighted by ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959,United States.Individual reprints(single or multiple copies)of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585(phone),610-832-9555(fax),or serviceastm.org(e-mail);or thr