TM_D_3683_
_11_rus_scan
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OHAe TexHn4ecknx pernaMeHTOB n cTaH-AapToB.CTeneHb cOoTBeTcTBnA-MoAnpoBaHHa(MOD)6 BBEAEH BNEPBbIEo6 K HacmogueMy cmaHdapmy ny e exeaodHoM-HoM yKa3amene HaquoHanLHbe cmaHoapmbi,a meKcm u3MeHeHuu u nonpaeok e exeMeCA4HOM UHpop-MauuOHHOM yka3amene HauuoHanLHble cmaHapmbi.B cnyuae nepecMompa(3aMeHbi)unu omMeHbIHacmou山ezo cmaHdapma coomeemcmeyiouwee yeedoMneHue 6ydem ony6nukoeaHo e exeMecA4HoM uHpop-MauuOHHOM yKa3amene HauoHanLHLIe cmaHapmbi.CoomeemcmeyouaR uHpopMauuA,yeedoMneHue umekcmbl pa3Mewalomc makke e uHpopMayuOHHOu cucmeMe obuwe2o nonb3oaHuA-Ha oQuuuanbHOMcaume OedepanLHo2o a2eHmcmea no mexHu4eckoMy pe2ynuposaHuio u Memponozuu e cemu VHmepHem CTaHAapTHopM,2015B Poccnicko Pegepaynn hacton ctaHgapt he Moxet 6bItb noNHOctbio unn yactn4hO Bocpon3Be-AeH,TpaxnpoBaH n pacnpocTpaHeH B Ka4ecTBe onnanbHoro 3gaHnA 6e3 pa3peweHnA egepanbHoroareHTcTBa no TexHnueckoMy perynpoBaHo n MeTponornOCT 32977-2014BBeAeHneMukpo3neMeHTbI cogepxatcA B opraHn4eckoi n MHepanbHo yactx yrnei.AKtyanbHOCtb n3yyeHngLeHHbIX TOKC4HbIX Mnkpo3neMeHTOB B TBepAbiX TonnnBax onpegengetcA TeM,4To B MHoroToHHaxHbIX npo-ueccax TonnBHoro texHonorwueckoro cnonb3oBaHn yrne nponcxognT pacnpegeneHne Mnkpo3neMeH-TOB B npogykTbI nepepa6oTkn yrnen n okpyalowyio cpegy.Ang geTanbHoro onepatuBHoro onpegeneHng cocTaBa n cogepkaHnA MKpo3neMeHToB B yrngx u npo-gyktax ux nepepa6otkn Tpe6yioTcA konM4ecTBeHHble,HcTpyMeHTanbHble,BbicoKonpon3BOAnTenbHble aHa-nnT4eckne MeToqbi.OAHnM u3 Taknx MeTogoB,nony4nBwnx pacnpocTpaHeHne B yrnexnMn4eckonaHantecko npaktuke,gBngeTcA nnameHHag aTomHo-a6cop6oHHaA cneKTpoMeTpnA.B HacToAeM cTaHgapte pernaMeHTnpoBaH aToMHo-a6cop6uOHHbi MeToA oqHOBpeMeHHoro onpege-neHna BoCbM MnKpo3neMeHtoB B 3one tBepgoro tonnnBa:6epunnng,xpoMa,MeAn,MapraHua,Hnkeng,cBnH-a,BaHagg HKa.HacToguu cTaHAapt rapMoHn3npoBaH c ASTM D 3683.MeToAnKa onpegeneHnA MnKpo3neMeHTOBpa3pa6oTaHa npnMeHnTenbHo k yrngm CWIA,u noka3atenn npeyn3noHHocTn MeToga paccuntaHbi gng nHtep-BanoB cogepxaHni MnKpo3neMeHToB,xapaktepHbix Ang yrnei CWA(Ta6nnybi 2 n 3).lockonbky Anana3oHbicogepxaHn MuKpo3neMeHToB B yrngx CWIA,Poccn n ctpaH CHT npnHynnnanbHo He oTnn4alotcA,npn pa3-pa6otke Hactogero ctaHgapta Ta6nnyb 2 3 6binn Bknio4eHbi B pa3gen 门pen3noHHOCTb 6e3 n3MeHe-H.Hactogwn ctaHgapt uMeet cnegyioune oTnn4ng o npuMeHeHHoTo B HeM HaLnoHanbHoro ctaHAaptaASTM D 3683:-B o6nactb pacnpoctpaHeHng BKnio4eHb Bce BAbi TBepgoro MnHepanbHoro tonnnBa;-npuBegeH nepe4eHb ccbino4HbiX cTaHAapToB,B ToM 4ucne MexrocygapcTBeHHble cTaHAaptbi Ha peak-TMBbI nocyAy;-pekomeHAyemag cteneHb n3Menb4eHng aHanntn4ecko npo6b(-250 MKM n-150 MKM)3aMeHeHa HaBenn4nHy,npnHATyio B MexAyHapoAHbix cTaHAapTax ISO n MexrocyqapcTBeHHbIX cTaHAapTax(-212 MKM).0CT32977一2014M E X rO C yA P C T B E HH bIC T A HA P TTOnnNBO TBEPDOE MNHEPANbHOEOnpeneneHne Mnkpo3neMeHTOB B 3one aToMHo-a6cop6uNoHHbIM MeTOAOMSolid mineral fuel.Determination of trace elements in ash by atomic absorption methodAaTa BBeneHNa-2016-04-011 06nacTb npnMeHeHNAHacTogwnn CTaHgapT pacnpocTpaHgeTca Ha KaMeHHble n 6ypble yrnm,nuaHumbl,aHmpauumbl,aopo-yue cnaHubl,KoKC,mopob,monnueHble 6pukembl,npooykmbl o6o2aweHua,nepepabomku u cxueaHua meep-do20 MUHepanbHo2o monnuea(danee-meepdoe monnueo)ycTaHaBnMBaeT aToMHo-a6cop6uNoHHbINMeTon onpeneneHNa MNkpoaneMeHTOB B 3one TBepnoro TonnNBa.K MWKpo3neMeHTaM OTHOCATCA 6epnnnwn,XpoM,Menb,MapraHeu,HWKenb,CBNHeL,BaHann N UNHK.npn o3oneHNn TBepAblx TonnMB B nabopaTopnn npn 500C yka3aHHble MnKpo3neMeHTbl KonwuecTBeHHOnepexonAT B 3ony,no3ToMy conepkaHne MNKpoaneMeHTOB,HanneHHoe B 3one,MoKeT 6bITb nepecyWTaHo HaWCXO Hoe TonnNBO.npn npoMblwneHHOM cKnraHnn TBepAblx TonnNB yacTb MNKpo3neMeHToB nonanaeT B oKpyKarowlyhocpeny c bIMOBbIMN ra3aMN,no3ToMy HanneHHoe B 3one TBepabIx ocTaTKoB W 3one yHoca conepxkaHne MVKpo-3neMeHTOB He Bcerna MoxkeT 6bITb nepecyMTaHo Ha NCXo Hoe TonnNBO.pMMe4aHMa1 non MWKpo3neMeHTaMn noHMMaIOT 3neMeHTbl,MaccoBa Aon KOTopbIX B cyXoM TBepAoM TonnNBe CocTaBnseTMeHee 0,1%(1000 ppm1).CMHOHNMbl TepMWHa&MNKpo3neMeHTbl-Manble 3neMeHTblx,cnenoBble 3neMeHTbI.2 B HacToRweM CTaHgapTe He npBegeHbl Tpe6oBaHna 6e3onacHOCTN,CBA3aHHble c npnMeHeHneM aToMHO-a6cop-6uMOHHoro cnekTpoMeTpa.npaBnna 6e3onacHon 3KcnnyaTaunn aTOMHO-a6cop6yMoHHoro cneKTpoMeTpa coAepxkaTca BAoKyMeHTauln K npnbopy.2 HopMaTNBHble ccbinknB HacToAweM CTaHnapte ncnonb3oBaHbl HopMaTNBHble cCbinKn Ha cnenylowne MexkrocynapcTBeHHbleCTaHnapTbl:TOCT OIML R 76-1-2011 TocynapcTBeHHas CncTeMa o6ecneyeHna eAHCTBa N3MepeHnn.Becbl HeaB-TOMaTN4eckoro neNcTBN9.HacTb 1.MeTponorwueckne n TexHwueckne Tpe6oBaHMA.VcnblTaHNaTOCT ISO 687-2012 TonnMBo TBepnoe MWHepanbHoe.KoKc.OnpeneneHne conepxaHna Bnarn B aHa-nWTNueckon npobe nng o6wero aHann3a2)TOCT ISO 1171-2012 TonnMBo TBepnoe MWHepanbHoe.OnpegeneHne 3onbHOCTM3)TOCT 1770-74(WCO 1042-83,VCO 4788-80)nocyna MepHas na6opaTopHaa cTeknaHHaa.UnnwH-apbl,MeH3ypkn,Kon6bl,npo6npkn.O6wne TexHNyeckne ycnoBna1)EanHnua n3MepeHnA KOHueHTpaunn ppm-(vacTen Ha MMnnMoH).1 ppm 1r/T=1 Mr/kr=1 MKr/r 10%.2)Ha TeppnTopnM Poccnnckon enepaumn AencTByeT TOCT 27589-91(MCO 687-74).M3 gaHne o中nunanbHoeFOCT 32977-2014OCT 3118-77 PeakTBbi.KncnoTa congHa.TexHneckne ycnoBngTOCT 4461-77 PeaKTBbi.KncnoTa a3oTHa.TexHn4eckne ycnoBOCT ISO 5068-2-2012 Yrnu 6ypbie n nrHnTbi.OnpegeneHne cogepaHn Bnarn.actb 2.KocBeH-Hbi rpaBnMetpnyecknn Metog onpegeneHA Bnarn B aHanutuyecko npo6e1)OCT 6563-75 M3genu TexHn4eckne u3 6naropogHbix MeTannoB n cnnaBoB.TexHn4eckne ychoBnAOCT 6613-86 Cetkn npoBono4Hble TKaHble c kBagpatHbiMn g4eikaMn.TexHn4eckne ycnoBngFOCT 6709-72 Boga AncTunnnpoBaHHa.TexHneckne ycnoB2)OCT 9656-75 PeaKTBbi.KncnoTa 6opHa.TexHn4eckne ycnoBnOCT 10484-78 PeakTnBbi.KncnoTa TopncToBogopogHa.TexHnueckne ycnoBnOCT 10742-71 Yrnn 6ypbie,KaMeHHble,aHTpaynt,ropio4ne cnaHybi n yronbhble 6puKeTbi.MeTogbioT6opa n nogroToBkn npo6 An na6opaTopHbIx cnbitaHFOCT 11303-2013 Topp n npogyktbi ero nepepa6otkn.MeTog npnroToBneHnA aHanntecknx npo6OCT 11305-2013 Topp n npogykTbi ero nepepa6oTkn.MeTobi onpegeneHg BnarnOCT ISO 11722-2012 TonnuBo TBepAoe MHepanbHoe.Yronb KaMeHHbi.OnpegeneHne Bnarn BaHanntneckon npo6e Ang o6wero aHann3a BbicywnBaHneM B Toke a3oTa3)OCT 13867-68 poAyKTb XMn4eckne.O603Ha4eHe 4NCTOTblFOCT 17070-2014 yrnn.TepMHbI n onpegeneHnOCT 19908-90 Turnn,yawn,ctakaHbi,kon6bi,BopoHkn,npo6npkn n HakoHe4Hnkn n3 npo3pa4HoroKBapueBoro cTekna.O6ne TexHeckne ycnoBAOCT 23083-78 Kokc KaMeHHoyronbhb,nekoBbi n tepMoaHTpaynt.MeToAbi oT6opa u nogrotoBknnpo6 An cnbiTaHOCT 25336-82 ocyga n o6opyAoBaHne na6opaTopHble cTeKnAHHbe.TNbI,ocHoBHble napaMeTpbIM pa3MepblOCT 27313-95(MCO 1170-77)TonnMBo TBepgoe MnHepanbHoe.O603Ha4eHMe noka3aTene Ka-yectBa n popMynbi nepecyeta pe3ynbTatoB aHan3a Ang pa3nn4HbIX cocToAH TonnnBap n M e y a H ne-p nonb3oBaHN HacTOLM cTaHAapToM enecoo6pa3Ho npoBepTL AeNcTBne ccbino4-HbIX cTaHAapToB B MHopMaunOHHOn cncTeMe o6ero nonb3oBaHMA-Ha onanbHoM canTe PegepanbHoroareHTcTBa no TexHnecKoMy perynnpoBaHnio n MerponorM B ceTH VHTepHeT wnn no exeroAHoMy nHPopMaOHHoMy yKa-3aTeno HaynoHanbHble cTaHgapTbi,KoTopbi onyonnKoBaH no cocToRHnIO Ha 1 HBap tekyero roga,n no BbinycKaMexeMecHoro HpopMaynoHHoro yxa3aTen HaOHanbHble CTaHAaPTbi 3a Tekyn rog.Ecnn cCbInOuHbI cTaHAapT3aMeHeH(3MeHeH),To np noNb3oBaHMM HacTOLM CTaHAapToM,cnegyeT pyKOBOACTBOBaTbC 3aMeHAIOWM(3MeHeH-HbIM)CTaHAapToM.EcnM ccbinoHbIM cTaHAapt oTMeHeH 6e3 3aMeHbI,To nonokeHne,B KoTopoM gaHa ccbinKa Ha Hero,npMeHeTc B acT,He 3aTparBalouen 3Ty ccbnKy.3 TepMHb n onpeeneHB HacToAeM cTaHAapTe npnMeHeHbI TepMHbI no OCT 17070.O603HayeHug noka3atene kayectBa n Hgekcbi K HuM-no OCT 27313.4 CyuHOCTb MeToAaCyHOCTb MeToAa 3aknio4aeTcA B cneAyioeM:-o3oniot npo6y TBepAoro tonnuBa np TeMnepatype(500 10)C;-KOn4eCTBeHHO 3BneKaloT MKpo3neMeHTbI 3 30Nbi nepeBogAt X B pactBop nyTeM pa3noxeHnA30NbI CMeCbiO KOHLeHTpnpoBaHHbIX congho,a3otho n 中TOpncToBOgopoAHo kncnot npu HarpeBaHnn Ha Bo-AHo aHe B npcyTcTB 6opHo KcoTbl;-onpeAengiot cogepxaHMe Mnkpo3neMeHTOB B pactBope MeToAOM aToMHo-a6cop6LnOHHON cneKTpo-MeTpMn.B Ta6nnue 1 npnBegeHbi ychoBng onpegeneHn MnkponeMeHToB aToMHo-a6cop6LMOHHbIM MeTOAOM caToMn3ayen B nnaMeHn:AnMHb BonH aHannT4ecknx nnH 3neMeHToB n coctaB ra3oBon cMecn An co3Aa-H nnaMeH.Ha reppnTopnn Poccnicko egepaunn gecByeT OCT P52917-2008(MCO 11722:1999,CO 5068-2:2007)TonnBo TBepAoe MHepanbHoe.MeTobi onpegeneHA Bnarn B aHant4ecko npobe.2)Ha reppuTopnn Poccnckon 中egepaunn gencrByer OCT P 52501-2005(MCO 3696:1987)Boga n na6opa-TopHoro aHan3a.TexHnueckne ycnoBA.3)Ha TeppnTopnn Poccnckoi eAepaunn geicTByeT OCT P 52917-2008(MCO 11722:1999,MCO 5068-2:2007)TonnBo TBepAoe MnHepanbHoe.MeTob onpegeneHA Bnarn B aHanTnecko npo6e.2