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TM_D_4614_
_11_2019
Designation:D461411(Reapproved 2019)Standard Specification forEthyl Acetate(All Grades)1This standard is issued under the fixed designation D4614;the number immediately following the designation indicates the year oforiginal adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.Asuperscript epsilon()indicates an editorial change since the last revision or reapproval.1.Scope1.1 This specification covers the various grades of ethylacetate suitable for use as solvents in paint and relatedcoatings.1.2 The values stated in SI units are to be regarded asstandard.No other units of measurement are included in thisstandard.1.3 The following applies to all specified limits in thisstandard:for purposes of determining conformance with thisstandard,an observed value or a calculated value shall berounded off“to the nearest unit”in the last right-hand digitused in expressing the specification limit,in accordance withthe rounding-off method of Practice E29.1.4 For specific hazard information and guidance,see thesuppliers Material Safety Data Sheet for material listed in thisspecification.1.5 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade(TBT)Committee.2.Referenced Documents2.1 ASTM Standards:2D268 Guide for Sampling and Testing Volatile Solvents andChemical Intermediates for Use in Paint and RelatedCoatings and MaterialD891 Test Methods for Specific Gravity,Apparent,of LiquidIndustrial ChemicalsD1078 Test Method for Distillation Range of Volatile Or-ganic LiquidsD1209 Test Method for Color of Clear Liquids(Platinum-Cobalt Scale)D1296 Test Method for Odor of Volatile Solvents andDiluentsD1353 Test Method for Nonvolatile Matter in Volatile Sol-vents for Use in Paint,Varnish,Lacquer,and RelatedProductsD1364 Test Method for Water in Volatile Solvents(KarlFischer Reagent Titration Method)D1613 Test Method for Acidity in Volatile Solvents andChemical Intermediates Used in Paint,Varnish,Lacquer,and Related ProductsD3545 Test Method for Alcohol Content and Purity ofAcetate Esters by Gas ChromatographyD4052 Test Method for Density,Relative Density,and APIGravity of Liquids by Digital Density MeterD5386 Test Method for Color of Liquids Using TristimulusColorimetryE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE300 Practice for Sampling Industrial Chemicals2.2 U.S.Federal Specification:3PPP-C-2020 Chemicals,Liquid,Dry,and Paste:Packagingof3.Properties3.1 Ethyl acetate shall conform to the requirements of oneof the grades in Table 1.4.Sampling4.1 The material shall be sampled in accordance withPractice E300.5.Test Methods5.1 The properties enumerated in this specification shall bedetermined in accordance with the following ASTM methods:5.1.1 Purity and Alcohol ContentTest Method D3545.5.1.2 Apparent Specific GravityDetermine the apparentspecific gravity by any convenient method that is accurate to1This specification is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings,Materials,and Applications and is the direct responsibility ofSubcommittee D01.35 on Solvents,Plasticizers,and Chemical Intermediates.Current edition approved April 1,2019.Published April 2019.Originallyapproved in 1986.Last previous edition approved in 2011 as D4614 11.DOI:10.1520/D4614-11R19.2For referenced ASTM standards,visit the ASTM website,www.astm.org,orcontact ASTM Customer Service at serviceastm.org.For Annual Book of ASTMStandards volume information,refer to the standards Document Summary page onthe ASTM website.3Available from Standardization Documents Order Desk,DODSSP,Bldg.4,SectionD,700RobbinsAve.,Philadelphia,PA19111-5098,http:/dodssp.daps.dla.mil.Copyright ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959.United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade(TBT)Committee.1 the third decimal place,the temperature of both sample andwater being 20 or 25 C(see Guide D268,or Test MethodD891 or D4052).5.1.3 Distillation RangeTest Method D1078 using a tem-perature measuring device having a range of 48 to 102 C anda resolution of 0.1 C.5.1.4 AcidityTest Method D1613.5.1.5 WaterTest Method D1364.5.1.6 ColorTest Method D1209.5.1.7 Nonvolatile MatterTest Method D1353.5.1.8 OdorTest Method D1296.6.Packaging and Package Marking6.1 Package size to be agreed upon between the purchaserand the supplier.6.2 Packaging shall conform to applicable carrier rules andregulations or,when specified