ASTM_D_5830_-_22.pdf

Designation:D583022Standard Test Method forSolvents Analysis in Hazardous Waste Using GasChromatography1This standard is issued under the fixed designation D5830;the number immediately following the designation indicates the year oforiginal adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.Asuperscript epsilon()indicates an editorial change since the last revision or reapproval.1.Scope1.1 This test method is used to determine qualitatively andquantitatively the presence of the following compounds inwaste samples using gas chromatography.This test method isintended for use as a screening method with a typical reportinglevel of 0.1%.DichodifluoromethaneTetrahydrofuranTrichlorofluoromethaneAcetone1,1,2-Trichloro-1,2,2-trifluoroethaneMethyl Ethyl KetoneMIBKMethanolCyclohexanoneEthanolEthyl AcetateIsopropanolPropyl Acetaten-PropanolButyl AcetateIsobutanolBenzenen-ButanolToluenetert-ButanolEthylbenzeneMethylene ChlorideXylenesChloroformStyreneCarbon TetrachlorideChlorobenzene1,1-DichloroethaneDichlorobenzenes1,2-DichloroethaneNitrobenzene1,2-DichloropropaneFluorobenzene1,1-Dichloroethylenen-Propyl Benzene1,2-DichloroetheneIsopropyl Benzene1,1,1-TrichloroethaneIsobutyl BenzeneTetrachloroethylenen-Butyl BenzeneTrichloroethylene2-EthoxyethanolTetrachloroethane2-ButoxyethanolCyclopentane2-Ethoxyethanol AcetatePentane2-MethoxyethanolHexaneBromoformHeptaneCarbitolCyclohexaneEthyl EtherIsooctane1,4-DioxaneNitropropaneDiacetone AlcoholEthanolamineAcetonitrileNitromethanePyridineEthylene ChlorideToluidineBenzyl ChlorideEthylene GlycolPropylene Glycol1.1.1 This compound list is a compilation of hazardoussolvents and other constituents that are commonly seen inhazardous waste samples.1.2 The scope of this test method may be expanded toinclude other volatile and semivolatile organic constituentssuch as but not limited to those described below,provided theintended use data quality objectives including sampling,recovery,and analytic data quality are demonstrated as satis-fied by the user.1.2.1 Hydrocarbon mixtures such as kerosene and mineralspirits.1.2.2 High-boiling organics,defined here as compoundswhich boil above n-Hexadecane.1.2.3 Other organics that the analyst is able to identify,either through retention time data or gas chromatography/massspectrometric(GC/MS)analysis.1.3 This standard does not purport to address all of thesafety concerns,if any,associated with its use.It is theresponsibility of the user of this standard to establish appro-priate safety,health,and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade(TBT)Committee.2.Referenced Documents2.1 ASTM Standards:2D1193 Specification for Reagent WaterD4547 Guide for Sampling Waste and Soils for VolatileOrganic CompoundsD4687 Guide for General Planning of Waste SamplingD5013 Practices for Sampling Wastes from Pipes and OtherPoint DischargesD5681 Terminology for Waste and Waste ManagementD5743 Practice for Sampling Single or MultilayeredLiquids,with or Without Solids,in Drums or SimilarContainers1This test method is under the jurisdiction of ASTM Committee D34 on WasteManagement and is the direct responsibility of Subcommittee D34.01.06 onAnalytical Methods.Current edition approved March 1,2022.Published March 2022.Originallyapproved in 1995.Last previous edition approved in 2014 as D5830 14.DOI:10.1520/D5830-22.2For referenced ASTM standards,visit the ASTM website,www.astm.org,orcontact ASTM Customer Service at serviceastm.org.For Annual Book of ASTMStandards volume information,refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959.United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade(TBT)Committee.12.2 EPA Documents:3TestMethod8000D DeterminativeChromatographicSeparations,SW-846,Revision 5,2018Test Method 8015D Nonhalogenated Organics Using GC/FID,SW-846,Revision 4,2003Test Method 8021B Aromatic and Halogenated Volatiles ByGas Chromatography Using Photoionization and/or Elec-trolytic Conductivity Detectors,SW-846,Revision 3,2014Test Method 8260D Volatile Organic Compounds by GasChromatography/Mass Spectrometry(GC/MS),SW-846,Revision 4,20183.Terminology3.1 DefinitionsFor definitions of terms used in thisstandard,refer to Terminology D5681.4.Summary of Test Method4.1 Waste samples are analyzed