ASTM_D_5599_-_17_rus.pdf

D5599-17 -STANDARD TEST METHOD FOR DETERMINATION OF OXYGENATES IN GASOLINE BY GAS CHROMATOGRAPHY AND OXYGEN SELECTIVE FLAME IONIZATION DETECTION 2017 ():21.09.2017:3268-17/ASTM -,.9,-49,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D5599-17 1 D5599-17 -1 D5599;,.().1.1.1 220C 130C.0,1%20%.1.2 ,.().-,.1 ASTM D02 ,D02.04.0L .1 2015.2015.1994.2010.D 5599-00(2010).DOI:10.1520/D5599-15.ASTM D5599-17 2 ,-,.,.1.3,.1.4 ,.,.1.5 -,(TBT).2.2.1 ASTM:2 D1298 ,2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.ASTM D5599-17 3 API D1744 (2016.)3 D4052 ,API()D4175 ,D4307 594 -,E1064 E1510 3.3.1:3.1.1 ,.3.1.2 ,.3.1.3 3 .www.astm.org.ASTM D5599-17 4 .4.4.1 ,1,2-().,.,-().6.4.2 .8.2.4.3 .1 ,1,2-,.5.5.1 .,.ASTM D5599-17 5 .5.2 ,.6.6.1 -,()-().-,Pt/Rh.(CO),:CxHyOz zCO+(y/2)H2+(x z)C(1)6.2 Pt/Rh -/,(,).6.3 ,-,:CO+3H2 CH4+H2O(2)CH4 .6.4 ,.350C ASTM D5599-17 6 450C,.2 ,.7.7.1 ,:7.1.1 ,.7.1.2 ,0,1 1,0 .,-.10:1 500:1.7.1.3 -.70 a(10 .),.,550 (80 .).7.2 ,-,ASTM D5599-17 7 .1.7.2.1 ,.1 E594,.1 7.2.2 :(a)103,(b)100 (ppm)(1 O/),(c)106 ,(d)0,1 1,0,(e).7.3 ,60 0,25,1,0,.,.7.4 Cn HmOx-*ASTM D5599-17 8 .:7.4.1 ,7.4.2 ,7.4.3 ,7.4.4 ,7.4.5 .8.8.1 .,.4 ,.8.2 :,-,-,-,-,-,-(),-(),-(),().(,).8.3 ,8.2,.8.2 4 ,DC.,.,BDH Ltd.,Inc.(USPC),.ASTM D5599-17 9 ,(,1,2-).8.4 ,-.().8.5,:8.5.1,-.(,).8.5.2,99,9%.().8.5.3 -,99,995%,95%/5%,.().8.5.4 ,.,.8.6 ,(),.9.9.1 .ASTM D5599-17 10 E1510.,.,7.3,.1.9.2 ,.,.1.,C 250 50C(.10),8/250C 350C 450C 850C 1300C,/-1 :300/H2:30/.(.,)H2:0,6/0,1 1,0 A 100 1 ,0,1%20,0%.,.,.0,5 100:1 .10.10.1 ,.2 ,60-ASTM D5599-17 11 ,.1.2.2.,(,.1)A,B B,C,D 5,33 32,0 D D 5,89 18,0 D D 6,45 32,0 0,70 0,98 7,71 46,1 0,99 0,97 8,97 60,1 1,28 0,96-10,19 74,1 1,63 0,99-11,76 60,1 1,30 0,98 12,73 88,2 1,90 0,97 13,92 74,1 1,59 0,97 14,53 102,2 2,26 1,00 15,32 74,1 1,64 0,99 15,49 102,2 2,25 0,99-15,97 88,1 2,03 1,04 1,2-16,57 90,1 1,00 1,00-17,07 74,1 1,69 1,03 18,23 102,2 2,26 1,00 A .B 1,2-.C .D .10.2 D4307 (,8.2),.(),.ASTM D5599-17 12 .99,9%.,D1744 E1064.1 .1.2 10.2.1 ,.0,1.,.,.0,1 ()2 -1,2-ASTM D5599-17 13 .20%,/.,.10.2.2 ,10.2.1.(,1,2-)0,1.2%6%.10.2.3,2 ,.10.2.4 .3 ,.10.3 ,.10.3.1 (rsps):rsps=(As/Ai)(3):ASTM D5599-17 14 As-,Ai-,(amts):amts=(Ws/Wi)(4):Ws-,Wi-,s.10.3.2 ,s,():rsps=(bo)(amts)+bl(amts)2(5):rsps-s(y),bo-s,amts-s(x),bl-.3 ASTM D5599-17 15 10.3.3 .3 .5.r2 .r2 0,99 .11.11.1 .11.2 ,.1 10 .0,1 .11.3 ,.0,1.2%6%,50.11.4,().,.,.11.5 (0,1 1,0),.,.11.6 ,.ASTM D5599-17 16 12.12.1 ,:12.1.1 ,.(rsps).3(10.3.1).12.1.2 (amts),(rsps).5(10.3.1).12.1.3 .6 .(6):ws-,amts-,12.1.2,Wi-,Wg-,.12.1.4 ,11 12.1.12.2 ,:ASTM D5599-17 17 12.2.1 .,.(rsps).3(10.3.1).12.2.2 (amts)(12.2.1).5(10.3.1).12.2.3 .6(12.1.3),.12.3 ,:12.3.1 :(7)(8):Ocal-,ws-,.6,Ns-,Ms-,.2,16.0-.ASTM D5599-17 18 12.3.2 ,:(9):Ouncal-,wsu-,Ns-,Ms-,.2,16.0-.12.3.3 ,.Otot=Ocal+Ouncal(10)12.4 ,0,01%.,0,1%.12.5 ,.11:(11):wi-,.6,Vi-,ASTM D5599-17 19 Di-15,56C(60F),.3,Df-,D1298 D4052.12.5.1,14,.ILS,14.3.15,56/15,5 6 C 0,7963 0,7939 0,7899-0,7922-0,8080 0,7460 0,8114 0,7282 0,8058 0,7452-0,8170-0,8137 0,7758 12.6 ,.3,0,01%.13.13.1 ,:13.1.1 :13.1.1.1 ,10.2,13.1.1.4.ASTM D5599-17 20 13.1.1.2 ,.13.1.1.3 .13.1.1.4 (R):,0,20 1,00 0,010+0,043C 1,00 12,00 0,053C 1,00 12,00 0,053C 0,20 20,00 0,069+0,029C 1,00 20,00 0,048C 1,00 20,00 0,074C 1,00 20,00 0,060C :=(Co+Cd)/2 R=|Co Cd|Co-,Cd-.13.1.2 ,.13.2 :13.2.1 100,0%6,0%1,0%,.13.2.2 ,ASTM D5599-17 21 .,13.2.2.2,13.1.1.4.13.2.2.1 1 100,.13.2.2.2 100,0%10,0%1,0%,.4.,.%.%ASTM D5599-17 22 13.3 ,.14.5 14.1 ,10,13 12 .1,2-:14.1.1 ,(.4).(MeOH)0,07(X0,49)A (EtOH)0,03(X0,92)(iPA)0,04(X0,54)-(tBA)0,05(X0,65)-(nPA)0,04(X0,35)0,05(X0,58)(sBA)0,03(X0,54)0,05(X0,65)(iBA)0,03(X0,79)0,04(X0,86)-(tAA)0,05(X0,41)5 -ASTM International RR:D02-1359.ASTM Customer Service serviceastm.org.ASTM D5599-17 23-(nBA)0,06(X0,46)0,04(X0,58)0,03(X0,93)A X .14.1.2 ,(.4).(MeOH)0,25(X0,86)A (EtOH)0,27(X0,80)(iPA)0,21(X0,71)-(tBA)0,20(X0,80)-(nPA)0,17(X0,88)0,10(X0,95)(sBA)0,17(X0,73)0,16(X0,71)(iBA)0,19(X0,83)0,25(X0,79)-(tAA)0,18(X0,55)-(nBA)0,22(X0,30)0,24(X0,69)0,13(X0,83)A X .14.2 .15.15.1;();(-);(-);-;(-).ASTM D5599-17 24 D02.04 (D 5599-15),.(1 2017.)(1).ASTM International -,.,.,.-ASTM International.,.,.ASTM International,100 Barr Harbor Drive,PO Box C700,