ASTM_D_5919_-_96_2011_rus_scan.pdf

MEXTOCYAAPCTBEHHbIN COBET No CTAHAAPTN3ALN,METPONOr CEPT中NKALN(Mrc)INTERSTATE COUNCIL FOR STANDARDIZATION,METROLOGY AND CERTIFICATION(ISC)FOCTMETOCyAAPCTBEHHbI33587-CTAHAAPT2015yrOb AKTBMPOBAHHbICTaHAapTHbin MeToA onpeAeneHA agcop6unOHHONcnoco6HOCT np Manbix KOHeHTpaunAxacop6npyeMbIx BeweCTBM3aHne onunanbHoeMocKBaCTaHAapTMHoPM2016T0CT33587-2015npeancnoBneLenn,OCHOBHble npMHunnbl M OCHOBHON nopanok npoBeneHna pa6oT no MexkrocynapcTBeHHon CTaH-AapTn3aynn yCTaHoBneHbI TOCT 1.0-92&MexrocynapcTBeHHa CNCTeMa CTaHnapTn3aywn.OCHOBHble no-noxkeHnA rOCT 1.2-2009&MexkrocynapcTBeHHa cncreMa CTaHAapTn3aywn.CTaHAapTbl MexkrocyAap-CTBeHHble,npaBnna n pekoMeHnaunn no MexkrocynapcTBeHHon CTaHnapTn3aunn.npaBnna pa3pa6oTKn,npMHATNA,npnMeHeHNa,O6HOBneHNA N OTMeHbICBeneHNA o cTaHnapTe1 nOAOTOBNEH enepanbHblM rocynapcTBeHHbIM yHNTapHbIM npeanpnaTneM(yn&BHMN CMT)HaOCHOBe CoOCTBeHHoro ayteHTNYHorO nepeBona Ha pyccknn 93bIK CTaHAapta,yka3aHHoro B nyHKTe 42 BHECEH enepanbHbIM areHTCTBOM no TeXHnyeCKoMy perynnpoBaHnlo n MeTponorn(PoCCTaHAapT)3 nPMHAT MexkrocynapcTBeHHbIM coBeTOM no cTaHnapTn3aunn,MeTponornn n cepTnonkaynn(npo-ToKon OT 27 OKTA6pa 2015 r.Ne 81-M)3a npMHATne nporonocoBann:KpaTkoe HaNMeHoBaHne CTpaHblKoA cTpaHbl noCokpaweHHoe HaNMeHoBaHMe HaLMOHanbHoro opraHan0MK(MC03166)004-97MK(MC03166)004-97no cTaHAapTn3auMMBenapycbBYToccTaHnapT Pecny6nkn BenapycbKa3axcTaHKToccTaHnapT Pecny6nMkn Ka3axcTaHKnpr3n9KGKblprbl3cTaHnapTPoccnaRUPoccTaHnapTTanxnKnCTaHTJTanNKCTaHnapT4 npnka3oM enepanbHoro areHTCTBa no TexHnyeckoMy perynnpoBaHno n MeTponornn OT 17 MapTa2016 r.Ne 174-CT MexkrocynapcTBeHHbin CTaHnapT TOCT 33587-2015 BBeaeH B AeNcTBMe B KauecTBe Ha-UNOHanbHoro cTaHnapTa Poccnnckon enepaunn c 1 anpena 2017 r.5 Hacroaunn cTaHnapT wAeHTw4eH cTaHnapTy ASTM D 5919-96(Reapproved 2011)Standard Prac-tice for Determination of Adsorptive Capacity of Activated Carbon by a Micro-lsotherm Technique for Adsor-bates at ppb Concentrations(CTaHnapTHaa npakTnka nna onpeneneHna ancop6uMoHHoM cnoco6HocTn aK-TWBNpoBaHHoro yrna nyTeM nocTpoeHNA N30TepMbl ancopounn npn Manblx KOHueHTpauMax ancoponpyeMbIxBe山ecTB),CTaHnapT pa3pa6oTaH KOMNTeTOM ASTM D28 AKTMBMpoBaHHbln yronb,n HenocpeACTBeHHyIO OTBeT-CTBeHHOCTb 3a pa3paboTky MeTona HeceT nonKoMMTeT D28.02 OueHKa xKnnKon da3bl.nepeBon c aHrnMnckoro 93blka(en).HanMeHOBaHne HacToAwero CTaHnapta N3MeHeHO OTHOCNTenbHO HaNMeHOBaHNA yKa3aHHoro CTaHnap-Ta ana npnBeneHna B CooTBeTCTBMe c TOCT 1.5-2001(noapa3nen 3.6).OonyManbHble 3K3eMnnapbl CTaHAapTa ASTM,Ha OCHoBe KoToporo nogroToBneH HacToawnn Mexkrocy-AapCTBeHHbIN CTaHnapT,n cTaHnapToB ASTM,Ha KoTopble naHbl CCbinKN,NMelOTCA B enepanbHOM MHoop-MayNOHHOM OHe TeXHNyeCKnx pernameHTOB N CTaHnapToB.CBeneHN O COOTBeTCTBMN MexkrocynapCTBeHHbIX CTaHnapToB CCbinoyHbIM CTaHnaptaM npnBeneHbI BononHNTenbHOM npnnoxkeHNN A.CTeneHb COoTBeTCTBMA-MAeHTWYHa(IDT)6 BBENEH BNEPBbIEVHobopMauug o6 u3MeHeHuAx K HacmoaweMy cmaHdapmy nyonukyemca e exe200HOM UHobopMauu-OHHOM yKa3 ameneHauuoHanbHble cmaHdapmbl,a mekcm u3 MeHeHuu u nonpaBoK一Be米eMeCA4HOMUHobopMauuoHHOM yka3amene HauuoHanbHble cmaHoapmbI.B cnyyae nepecMompa(3aMeHbl)unu om-MeHbI Hacmoaweao cmaHdapma coomeemcmeylowee yeedoMneHue oydem onyonukoBaHo 6 exkemecayHOMUHopopMauuoHHOM yKa3amene HauuoHanbHble cmaHdapmbl.Coomeemcmeyiowaa uHobopMauua,yeedoM-neHue u mekcmbl pa3Mewaromca makke 6 UHobopMauuoHHou cucmeme oowe2o nonb30BaHua-Ha oobu-uuanbHOM caume DedepanbHo2o azeHmcmea no mexHuyeckoMy peaynupoeaHuio u Memponoauu e cemuVHmepHemCTaHAapTMH中opM,2016B Poccnnckon enepaunn HacToawnn cTaHnapT He MoxKeT 6bITb nonHOCTblo wnn yaCTNYHO Bocnpon3-BeneH,TupaxnpoBaH w pacnpocTpaHeH B KaueCTBe oopnunanbHoro n3naHna 6e3 pa3peweHna enepanbHoroareHTCTBa no TexHN4eCKoMy perynnpoBaHnio M MeTponornnFOCT33587-2015MEKOC YA A PC TBEHHbIMC TA HAAPTyrOJb AKTMBMPOBAHHbIMCTaHAapTHbI MeToA onpegeneHng acop6unOHHo cnoco6Hoctn npn Manbix KoHeHTpaunAxancoponpyeMbIx BeweCTBActivated carbon.Standard method for determination of adsorptive capacity for adsorbates at trace concentrationsAaTa BBeAeH-2017-04-011 06nactb npMeHeHA1.1 HacTow craHAapT ycTaHaBnnBaet meTog oyeHkn cnoco6HOcT aKTnBpoBaHHoro yrnA agcop-6npoBaTb KoMnoHeHTbi,cogepxawneca B Boge n cTo4HbiX Bogax B Hn3knX KoHyeHTpaynAx,nyTeM nocTpoe-HA n30TepMbi agcop6yn.MeTog npMeHHoT An xapaKtepncTKn agcopyOHHbIX cBOcTB HeOTpaoTaH-HbIX BOCCTaHOBneHHbIX aKTBpOBaHHbIx yrnen.1.2 HacToAw MeTog ncnonb3yioT B cpegax c cogepxaHnem agcoponpyemoro BewecTBa Ha ypoBHeManbIX 3HaeH MnnrpaMMOB Ha nTp n MKporpaMMOB Ha nnTp.1.3 Hactow metog moxet 6bITb cnonb3oBaH An onpegeneHn agcop6ynOHHOn cnoco6HOcTn ak-ThBpoBaHHbix yrne n KoHcTaHt ypaBHeHnA agcop6ynn 中peHAnnxa,npn ycnoBun npoBegeHn npoueAypB CTporoM COoTBeTCTBM c Tpe6oBaHAM AaHHoro cTaHAapTa.1.4 B HacToueM cTaHgapTe Bce eAnHnbI n3MepeHnA npnBeAeHbi B cncTeMe C.HnKakne ApyrneeAHb 3MepeH B HacTOw cTaHAapT He BKn4eHb.1.5 B HacToueM cTaHAapTe He npeAycMoTpeHO paccMOTpeHe Bcex BonpocoB o6ecne4eHMA 6e3-onacHOCTM,CBa3aHHbix c ero cnonb3oBaHneM.lonb3oBaTenb cTaHgapTa HeceT oTBeTCTBeHHOCTb 3a o6e-cne4eHne cOoTBeTCTByIounX Mep 6e3onacHOCT n oxpaHbi 3AOpoBba n onpegengeT yenecoo6pa3HOCTb np-MeHeHA 3aKoHogatenbHbix orpaHn4eH nepe ero cnonb3oBaHnem.2 HopMaTBHble cCbInKnAng npuMeHeHnA HacTowero cTaHAapTa Heo6xoAnMbi cnegyioune ccbino4hble gokyMeHTbi.Ang HeAa-TpoBaHHbIX cCbinoK npnMeHioT nocneHee n3aHne ccbino4Horo goKyMeHTa(Bknio4a Bce ero 3MeHeHn).2.1 CTaHAapTbI ASTM1)ASTM D 1129 Terminology Relating to Water(TepmHonorn,oTHocauacA K BoAe)ASTM D 1193 Specification for Reagent Water(Cneyn中nKayna na6opaTopHon BoAbi)ASTM D 3370 Practices for Sampling Water from Closed Conduits(门lpakTnkn or6opa npo6 Bogbi n33akpbITbIX BOAB0AOB)ASTM D 2652 Terminology Relating to Activated Carbon(TepMnHonorn,oTHocawaAcA K aKTBnpo-BaHHOMy yrno)ASTM D 2867 Test Methods for Moisture in Activated Carbon(MeTogLi onpegeneHn Bnarn B aKTnBM-pOBaHHOM yrne)1)YTo4HNTb ccbInKn Ha cTaHAapTbi ASTM MoKHo Ha caiite ASTM:www.astm.org unu B cnyx6e noAepxkn knn-eHTOB ASTM:serviceastm.org.B nHpopMaLNOHHOM ToMe exerogHoro copHnKa cTaHAapToB(Annual Book of ASTMStandards)cneAyeT o6pauaTbcA K cBoAKe cTaHAapToB exeroAHoro copHnKa cTaHAapTOB Ha cTpaHne caviTa.M3AaHne opnunanbHoeOCT33587-20153 TepMHbI onpeeneH3.1 OnpegeneH3.1.1 OnpegeneHna tepMnHOB,OTHocaXc K aKTnBnpoBaHHbiM yrnM nCnonb30BaHHbIX B HacTog-eM CTaHAapTe,npBeAeHbi no ASTM D 2652.3.1.2 OnpegeneHng TepMnHoB,Kacaowxc BoAbi n cnonb3oBaHHbiX B HacToqem cTaHAapte,np-BeAeHbI no ASTM D 1129.4 CyuHOCTb MeToga4.1 CyHOCTb MeToga 3aknio4aeTcA B onpegeneHnn agcopoyNOHHO cnoco6HOCTn aKTnBpoBaHHoroyrng nytem nomeweHng ero B eMKoctb,3anonHgeMyo npakTn4eckn goBepxy BOAHbiM pacTBOpom,cogepxa-M acoponpyemble BeecTBa,n onpegeneHnn KonnecTBa agcoponpyeMbIx BeecTB,yAaneHHbIX n3 pac-TBopa.lo pe3ynbTaTam CnbITaHg BbyncnioT agcopOyOHHyO aKTBHOCTb,CTpot n3oTepMy agcopOunn nrpapnecKnM cnoco6om onpeAenAioT KOHCTaHTbI ypaBHeHnA 中peHAnnxa K n 1/n.4.1.1 Maccy HaBeckn aKTnBnpoBaHHoro yrng,ncnonb3yemyo AnA ncnbiTaHnA,nog6npaoT TaKnM o6-pa30M,4T06bi A0CTn4b npeMneMbiX OCTaTO4HbiX KOHyehTpayn agcoponpyeMbix BewecTB B pacTBope.pnnpaBnnbHo nogo6paHHbix haBeckax aKtuBnpoBaHHoro yrng n3 pactBopa gonxHo yAangTbcA He 6onee 90%,HO He MeHee 10%acoponpyeMbIx BeeCTB.4.1.2 Ecnn Macca HaBeckn akTnBnpoBaHHoro yrng,yAoBneTBopowa yKa3aHHbiM yCnoBnAM,oKaeT-cA MeHee 1 Mr,06bem BoAHoro pactBopa mOHO yBenM4nTb,Hanpumep,go 1000 cM3.5 Ha3Ha4eHne n npnMeHeHe5.1 HacToA meTog no3Bonget onpegentb paBHoBecHyio agcop6yOHHyo cNOco6HOCTb aKTBPo-BaHhoro yrng no oThoweHnio k agcoponpyeMbiM BeecTBam,cogepKawMCA B Boge.KoHCTaHTbI ypaBHeHOpeiHgnnxa K u 1/n,Bbi4ncngemble,ncxoga n3 gaHhbix,nony4eHHbix hactoqwm Metogom,Moryt 6bitb nc-nonb3oBahbi Anq oyeHkn Tpe6yemoro konn4ecTBa aKTnBnpoBaHHoro yrnq n nepnogn4HocTn ero 3ameHbi npnouncTke BoA,cogepxawnx Apyrne KoHueHTpaunn acoponpyeMbix BeecTB.6 OrpaHn4eHn6.1 Boga He gonHa cogepkaTb HepacTBopMbix npMecen.6.2 ccnegoBaHna noka3ann,4To npncyTcTBne B Boge npupoAHbix opraHn4ecKnx BeectB,TaKnX KaKryMnHOBble KnCnoTb,MOKeT oKa3biBaTb 3Ha4nTenbHoe BnnAHne ha cnoco6Hoctb yrnei ancoponpoBatb Apy-rme BeuwectBa.Pe3ynbtatbi,nonyyehhble An BoAbi,cteneHb ncTOTbi KoTopoN oTnn4ha o ctenehn nCToTbIBoAbi Ang ahann3a,Moryt Obitb He npmehmbi ng Apyrnx BoAhbix CcTeM.6.3 Ha pe3ynbtatbi,nony4aemble HacTownm MeTogom Ana noctpoehng n3oTepMbi agcopoynn,Bnn-OT nOHHa cna,pH n TemnepaTypa BoAbi,a TaKke npncyTcTBne n pa3BnTne B BOAe MnKpoopraHn3MOB.7 Annaparypa7.1 lepeMewnBaiowee ycTpoicTBo,npncnoco6neHHoe AnA ycTaHoBKn B HeM 3OTepMn4ecknX cKnA-Hok n nepeMeunBaHn x cogepxnmoro go nony4eHnA oAHOpoAHon B3Becn nopowka aKTBpoBaHHoro yrnB Boge nyTem BcTpaxnBahna unn nepeBopa4nBaHng 3Tx cKngHoK,coBepwaiowee 25 ABnxeHn B MnHyTy.7.2 V3Menb4ntenb,cnoco6Hbi 3Menb4atb matepnan taK,4To6bi 90%matepnana npoxoguno yepe3CTO 325 Mew(45 MKM).7.3 V30TepMn4eckne cknHKn-cKnAHKn 3 qHTapHoro(TeMHoro)cTekna c y3KnM ropnoM n KPbIKaMn,repMeT4HO 3aKpbiBaoM cKnAHKn narogapa nonTeTpaTop3TneHOBLIM(TeOnOHOBbIM)BKnaAbIwaM,BMeCTMOCTb 250,500 n 1000 cM3,KoTOpble MOKHO noMeatb B yeHTpn中yry,Bpawaiowyoca co ckopo-CTbHO 2000 06/MH.7.4 lntaowni pe3epByap Ana pactBopa-KoHTeiHep BMectnMOCtbio 10 AM3 n3 HepxaBeowe cTa-nn 316 c nnaBaoen Kpbiwon,o6nnoBaHHo TenoHoM,cHaxeHHLin WapoBbiM KnanaHoM n3 HepxaBeo-we cranu 316 Ang perynupoBkn notoka npn 3anonHeHn n3oTepmn4ecko cknHkn(7.3).7.5 Becbi c npegenom Aonyckaemo norpewHOcT 0,1 Mr.2FOCT33587-20157.6 Cywnnbh wka中 c npnHyAutentho yupkynayne Bo3gyxa,cnoco6hbi noggepxnBatb Temne-parypy o 250 C.7.7 LeHTpu中yra c uacroTo BpaweHn 2000 06/MH,npnrogHa Ang pa3MeweHnA B He n3oTepmn4e-CKX CKnHOK BMeCTMOCTb Ao 1 AM3.7.8 MarHnTHble mewankn n meTannnueckne 6pycoukn,ncnonb3yemble Ang nepemewnBaHnA Ha Mar-HMTHbIX MewanKax.8 PeaKTMBbl8.1 Boga ucTnnpoBaHHa,Tun ll no ASTM D 1193.8.2 MeTaHoN BbicoKo cTeneHn 4ncTOTbi(04WeHHb MeTOgOM BbICoK3中eKTBHO AKOCTHOnxpoMaTorpaun).8.3 OAH0CHOBHbi ocat Kan(KH2PO4),pacTBop 1 Mon/AM3.8.4 nApoKcnA HaTpn(NaOH),pacTBop 1 Monb/AM3.9 lpoueAypbi oncTKn9.1 Hacoqw Meog ncnon3yiot Ang onpegeneHn agcopoyoHHo aKtBHOCt aKTnBnpoBaHHoroyrng no oTHoweHnio K agcoponpyeMbim BewecTBam,cogepxawMcA B Boge B KOHueHTpaunAx Ha ypoBHeppb2)(MKr/AM3).lo3toMy Bce o6opyAoBaHne n cTeKnAHHyo nocyAy,conpnKacaouwnecA np cNbITaHnn caktnBnpoBaHHbim yrnem nnn o4nwaemon Bogon,twatenbho o6pa6atbiBaiot Ana o4nctkn o cnegoB oprahn-ecknx coeAnHeHn.9.2 O6opyAoBaHne n nocygy ounuaioT B cooTBeTcTBnn c peKoMeHAaynAMn EPA(Environmental Pro-tection Agency-AreHTcTBo no 3auute oxpyxalouei cpeAbi),AaHHbiMn An aHanuTuecknx meTogoB onpe-geneHna 3arpa3HeHnn,a umeHHo:06paatbiBaiot nocneAoBatenbho ropqyen Bogon,Molownm cpeAcTBoM,AcTnnnpoBaHHo Bogon n pacTBopTeneM(MeTaHonoM BbIcoKon cTeneH nCToTbi),a 3aTeM BbICynBaOT.9.3 CTeknAHHyio nocyAy cywaT B cywnbHoM wkapy npn Temneparype 250 C He MeHee 1 4.3gennan3 TenoHa n HepaBeiowen crann cywat npn Temneparype 110 C B Te4eHne 1 4.10 ogroToBka aKtBnPoBaHHoro yrng10.1 B HacTouwem MeToge ncnonb3yioT xopowo nPOMbITbI aKTBnPoBaHHbi yronb,3Menb4eHHbigo npoxoxgeHnA He meHee 90%actny yepe3 cuTo 325 mew(45 MKM),noABeprHyTbin mokpoMy npocenBa-HMHO M 3KBBaneHTHOMy cnoco6y pacceBa.10.2 B 4eTbipe cKnAHKn(7.3)BMeCTnMOCTbI 250 CM3 Kaxga nomewaoT np6nn3TeNbHO no 25 rnopowkoo6pa3Horo aKTBnpoBaHHoro yrn.OcTaBwnc 06bem cKnAHKn 3anonHoT AucTnnnpoBaHHOMBOgo.10.3 CKnAHkn repMeT4HO 3aKpbiBaioT KpbIwKaMn n 3-5 pa3 nepeBopaynBaiot Ang nepemewnBaHngcogepnMoro.10.4 CknAHkn noMewaHoT B yeHTpnyry n npn ckopocTn BpaeHnA 2000 06/MH BbIAep*BalOT15 MMH,4T06bi gatb aktnBnpoBaHHomy yrno ocectb ha AHo cknHoK.He oceBuwnn ha AHo nopowok cnnBa-oT n noBTopAoT eHTpyrnpoBaHne go tex nop,noka BepxHn con BOAbi B cKnAHKax He cTaHeT YCTbIM.Aaot aKTBpoBaHHoMy yrnio ewe HekoTopoe BPeMA oTCTOATbcA gekaHTupyoT nAKOCTb,HaxogwyocAHaA ocaAKoM.10.5 BnaxHbM aKTBpoBaHHbin yronL BbicywnBaoT B cywnnLHoM wKa中y npn Temneparype 110 AonOCTOAHHO Maccb n nepeHocAT B 3KKaTop Ang ocTbiBaH.10.6 AnLTepHaTBHO aKTBpoBaHHbi yron nPoMbIBaoT 3KcTpakye B annapate CokcneTa c Anc-TunnpoBaHHo Bogo(8.1)B Te4eHne 1 Hegenn.10.7 BbIcyWeHHbIn aKTnBnpoBaHHbin yron nepeHocAt B aHKn n3 KopnHeBoro 6opocnnKaTHoro cTeK-na BMeCTnMOCTbio 1 Am3 c TepnoHoBbiMn BKnaqbiWaMn B Kpbiwkax n go ncnonb3oBahnA xpahAt B HepTHOMaTMocpepe,HanpMMep,B aTMocpepe a3oTa.2)ppb-parts per billion(uncno uacTei Ha munnnapA).3