ASTM_D_6647_-_01_2011_rus_scan.pdf

MEXKTOCYAPCTBEHHbIN COBET NO CTAHAAPTN3AUNN,METPONOTNN W CEPTNONKAUNN(MrC)INTERSTATE COUNCIL FOR STANDARDIZATION,METROLOGY AND CERTIFICATION(ISc)rOCTMEKOCyAPCTBEHHbIM33580一CTAHAAPT2015yronb AKTNBNPOBAHHbINCTaHnapTHbIn Meton onpeneneHna pactBopnmoroB KNcnoTe xene3a aToMHo-a6cop6uNoHHoNcneKTpoMeTpnenM3 naHne o中nunanbHoeMockBaCTaHnapTMHopM20160CT33580-2015npeancnoBneLenn,OCHOBHble npNHunnbl WOCHOBHoN nopanoknpoBeneHna pa6oT no MexkrocynapcTBeHHoN cTaHnap-TH3auwn ycTaHoBneHbl B rOCT 1.0-2015&MexrocynapcTBeHHa CncTeMa CTaHnapTn3auwn.OCHOBHblenonoxeH rOCT 1.2-2015MexkrocynapcTBeHHa CncTeMa cTaHnapTn3aunn.CTaHnapTbl MexkrocyAap-CTBeHHble,npaBnna n pekoMeHnaunn no MexkrocynapcTBeHHon CTaHnapTn3aunn.npaBnna pa3pa6oTKn,npn-HATNA,O6HOBneHNA N OTMeHbICBeneHNA o cTaHnapTe1 nOOTOBNEH enepanbHblM rocynapcTBeHHbIM yHMTapHblM npeanpnaTneM BcepoccnncKnnHay4HO-ccnenoBaTenbCKNN NHCTNTyT CTaHnapTn3 aUNN MaTepnanoB TexHonorn(yTBHVN CMT)】Ha oCHOBe CobCTBeHHoro ayTeHTWYHoro nepeBona Ha pyccKNN 93blK CTaHnapta,yka3aHHoro B nyHKTe 52 BHECEH enepanbHblM areHTCTBOM no TexHnyeCKoMy perynupoBaHnio nMeTponornn(PoCCTaHAapT)3 nPMHAT MexrocyAapcTBeHHbIM coBeTOM no cTaHAapTn3aunn,MeTponornn n cepTnonkaunn(npo-TOKON OT27oKT96p92015.N81-)3a npNHATNe nporonocoBann:KpaTkoe HanmeHoBaHne cTpaHblKon cTpaHbl noCokpaweHHoe HanMeHoBaHne HaunoHanbHoro opraHan0MK(MC03166)004-97MK(MC03166)004-97no cTaHnapTw3auMnBenapycbBYToccTaHnapT Pecny6nnkn BenapycbKa3axcTaHKZoccTaHgapT Pecnyonnkn Ka3axcTaHKnprn3N9KGKblprbl3cTaHAapTPoccnaRUPoccTaHgapTTaKnKNCTaHTJTamKnKCTaHnapT4 npwka3oM enepanbHoro areHTCTBa no TexHNyeckoMy perynnpoBaHno n MeTponorn OT 17 MapTa2016r.No 150-CT MexkrocynapcTBeHHbIN cTaHnapT rOCT 33580-2015 BBeneH BneNcTBMe B KayecTBe Hauno-HanbHoro cTaHnapTa Poccnnckon enepaunn c 1 anpena 2017 r.5 HacToawnn cTaHnapT naeHTwueH cTaHnapTy ASTM D 6647-01(Reapproved 2011)Standard TestMethod for Determination of Acid Soluble Iron Via Atomic Absorption(CTaHnapTHbIN MeTon onpeneneHna pac-TBopNMoro B KNcnoTe xene3a aToMHoN a6cop6unen)CTaHAapT pa3pa6oTaH KOMMTeTOM ASTM D28 AKTMBNpoBaHHbin yronb,N HenocpeAcTBeHHyIo OTBeT-CTBeHHOCTb 3a pa3pa6oTky MeTona HeceT nonKoMNTeT D28.02 OueHka xnakon da3bl.nepeBon c aHrnwnckoro 93blka(en).HanMeHoBaHne HacTogwero cTaHnapta N3MeHeHo OTHOCNTenbHO HaNMeHoBaHNA yKa3aHHoro cTaHnap-Ta ana npnBeneHNa B cooTBeTCTBMe c TOCT 1.5-2001(nonpa3nen 3.6).OonuwanbHble 3K3eMnnapbl CTaHnapTa ASTM,Ha oCHoBe KOToporo noAroToBneH HacTogunn Mexrocy-napcTBeHHbIN cTaHnapT,WcTaHnapTOB ASTM,Ha KoTopble naHbl ccblnkn,WMelOTCA B enepanbHOM MHcbopMa-LNOHHOM oHne TexHNyecKnx pernaMeHToB N cTaHnapToB.CBeneHNa o COOTBeTCTBNN MexkrocynapcTBeHHbIX cTaHnapToB cCbInoyHbIM CTaHnapTaM ASTM npnBe-eHbl B nononHNTenbHOM npnnoxkeHNN DA.CTeneHb CooTBeTCTBNA-MAeHTMYHa(IDT)6 BBENEH BNEPBbIEMHobopMauua o6 u3MeHeHUAx K HacmoaweMy cmaHdapmy nyonukyemca B exke200HOM UHobopMauuoH-HOM yKa3amene HauuoHanbHble cmaHdapmbl,a mekcm u3MeHeHuu unonpaBok-B exkemecAYHOM UHobop-MauuoHHOM yka3amene HauuoHanbHble cmaHdapmbl.B cnyuae nepecmompa(3aMeHbl)unu omMeHbIHacmoqwe2o cmaHdapma coomeemcmeylowee yeedoMneHue bydem onyonukoeaHo e exeMecauHOMUHobopMauuoHHOM yka3amene HauuoHanbHble cmaHdapmbl.Coomeemcmeylowas UHobopMauua,yee-doMneHue u mekcmb1pa3 Mewaiomc9maK米e B UHg中opMa4 OHHOcucmeme o6ue20nonb3 oBaHUA一HaO中U-uuanbHOM caume edepanbHo2o a2eHmcmea no mexHuyeckoMy peaynupoeaHuio u Memponoauu 6 cemuVHmepHem(www.gost.ru)CTaHAapTMHO中opM,2016B Poccnnckon enepaunn HacTogunn cTaHnapT He MoxeT 6bITb nonHoCTblo nnn yacTM4HO Bocnpon3-BeneH,TNpaxknpoBaH w pacnpocTpaHeH B KayecTBe oonunanbHoro w3naHNa 6e3 pa3peweHna enepanbHoroareHTCTBa no TeXHNyeckoMy perynnpoBaHnlO N MeTponorNFOCT 33580-2015ME KOC yAAPCTBEH HbIMC TAHAPTyOJb AKTMBMPOBAHHbIMCTaHAapTHLIN MetoA onpeAeneHA pacTBopuMoro B kncnote xene3aaToMHo-a6cop6noHHo cneKTpoMeTpneActivated carbon.Standard test method for determination of acid soluble iron via atomic absorption spectrometryAaTa BBeAeH-2017-04-011 06nactb npnMeHeHg1.1 Hactogwn cTaHgapt ycTaHaBnuBaet Metog onpegeneHnA cogepxaHng pactBopnMoro B KncnoTexene3a rpaHynnpoBaHHbIx n nopowkoo6pa3HbIX aKTnBnpoBaHHbIx yrne c ncnonb3oBaHMeM aToMHo-a6cop6-uoHHo cnekTpoMeTpnn c npAMo acnnpaye.An 3kcTpakun xene3a ncnonb3yioT congHyio KncnoTy.Hactogwu MetoA He npeAHa3HayeH HenocpeActBeHHo Ang onpegeneHnA o6wen KoHLeHTpaunn xene3a Bnpo6e.1.2 B HacTogueM cTaHgapte He npeAycMoTpeHO paccMOTpeHne Bcex BonpocoB o6ecne4eHn 6e30-nacHocT,cB3aHHbix cero cnonb3oBaHeM.onb3oBaTenb cTaHgapTa Hecet oTBeTCTBeHHOCTb 3a obecne-yeHMe cOoTBeTCTByOMX Mep 6e3onacHOCT oxpaHbI 3AOpoBbA onpegenget uenecoo6pa3HOcTbnpuMeHeHnA 3aKoHogaTenbhbix orpaHn4eHnnepeg ero cnonb3oBaHeM.Mepbi npeAocTopoxHOCTs npuBe-AeHbl B pa3Aene 8.2 HopMaTBHble ccbInKnAng npuMeHeHng Hactoguero ctaHAapta Heo6xoguMbi chegyiouwne ccbino4Hble gokyMeHtbi.Ang Hega-TpoBaHHbiX ccbinoK npnMeHgioT nocneAHee n3qaHne ccbino4Horo gokyMeHTa(Bknio4ag Bce ero n3MeHeHng).2.1 CTaHAapTbI ASTM1)ASTM D 2652 Terminology Relating to Activated Carbon(TepmnHonornA,oTHoca山ac K aKTuBnpoBaH-HoMy yrnHo)ASTM D 1193 Specification for Reagent Water(Cneynpnkauua na6opaTopHo BoAbi)ASTME11 Specification for Woven Wire Test Sieve Cloth and Test Sieves(Cneu中nKaun Ha npoBono4-HyHO cToTKaHb cnbITaTenbHble cTa)ASTME 177 Practice for Use of the Terms Precision and Bias in ASTM Test Methods(pakTuka ncnonb-30Bahu tepmnhoB npeln3noHHoct n otknoHehug B Metogax ncnbitahn no ASTM)ASTM E 287 Specification for Laboratory Glass Graduated Burets(Cneun中nKaynA cTeKnHHLIX rpagyn-pOBaHHbIX na6opaTopHbIX 6HopeToK)ASTM E 288 Specification for Laboratory Glass Volumetric Flasks(Cneyn中nKauA cTeKnAHHbIX MePHbIXna6opaTopHbIx Kon6)ASTME 300 Practice for Sampling Industrial Chemicals(paKTuKa oT6opa npo6 npoMbIWneHHLIX XnMM-yecknx npoAykToB)1)YTO4HNTb CCbUIKn Ha cTaHgapTbi ASTM MoHO Ha cavite ASTM:www.astm.org nnn B cnyx6e noggepxkn knMeH-ToB ASTM:serviceastm.org.B nHpopMaunoHHoM ToMe exerogHoro c6opHnKa cTaHgapToB(Annual Book of ASTMStandards)cnegyer o6pauaTbc K cBogke cTaHgapToB exerogHoro c6opHnKa cTaHgapToB Ha cTpaHnue caviTa.M3aHne onunanbHoeFOCT33580-20152.2 ly6nnka4 NISTCircular 602 Testing of Glass Volumetric Apparatus(cnuITaHnA cTeKnAHHo Mephoi nocyAbi)2)3 TepMnHbI n onpegeneHn3.1 B HacToAeM cTaHgapte npuMeHeHbi TepMMHbI no ASTM D 2652,a Takke cnegylown TepMnH cCOoTBeTCTByHOM onpegeneHeM:3.1.1 aToMHa a6cop6ng(atomic absorption):B nnaMeHHo aToMHo-a6cop6ynOHHo cneKTpo-MeTpun npo6y pacnbingiot B nnamg n aToMM3upyiot.CBeToBo notok npoxogt yepe3 nnamg u nonagaet BMoHoxpoMaTop n Ha geTektop,koTopbin onpegenget KonnectBo cBeta,nornoweHHoro aToMM3POBaHHbIM3neMeHTaMn B nnaMeHn.lockonbky kaxqbi MeTann MeeT co6cTBeHHyio XapakTepHyo eMy AnHy BOnHbInornoweHug,To ncnonb3yiot namny-3ny4atenb Ang gaHHoro 3neMeHTa.Kon4ecTBo 3Heprn npu xapakTep-ho gnuhe Bonhbi,nornouweHho B nnamehn,nponopynoHanbHo koHeHTpaynn 3neMeHta B npo6e B orpahn-4eHHOM AMana3oHe KOHLeHTpau.4 CyuHOCTb MeToga4.1 pegcTaBuTenbHyio npo6y Matepnana gna aHann3a oT6npaioT no ASTM E 300.po6y onpegeneH-HOn Maccb 3Menbyaot TaknM o6pa3oM,4To6bl He MeHee yeM 95%Maccbi npo6bi npoxognno yepe3 cnTo325 Mew.3Menb4eHHyio npo6y cywat B cywnnbHoM wkapy u 3aTem cMewnBaiot c pa36aBneHHoi congHokncnoton.PactBop KnnAtAt B teyeHne 5 MnH go o6pa3oBaHnA pactBopMbIx xnopgoB xene3a,3aTeM oxnax-gaiot u 中unbtpyiot.OcTatKn Ha 中nnbtpe npoMbiBaiot BoAon.3aTeM 中nbTpat Kon4ecTBeHHO nepeHocAt BcTaKaH.KOHLeHTpaynio Kene3a B OnLTpate n3MepAIoT MeTogoM aToMHoa6cop6unn,ncnonb3yA cTaHAapt-Hble pacTBopb.KoHueHTpaunio pacTBopnMoro B KncnoTe xene3a pacc4NTbIBaIOT OTHOCNTeNbHO MaccblcoAHo npo6bl.5 Ha3HayeHne n npnMeHeHne5.1 门pu ucnonb3oBaHnn aktnBnpoBaHHoro yrng B npoeccax kncnotho onctkn,o6pa6otkn kncnbixnnLeBbix npogyKToB,XnMn4eckon o4nctkn,ocBetneHna n Ap.,To ectb B npoueccax,B koTopbix xene3o MOkeTBbi(enaynBatbca u3 yrn,npnmehehne otMbitbix kncnotonyrnen ymehbwaet nnn nonhoctbio npegotBpaw,a-eT 3axBaT LBeTa B CTO4HbIX Bogax n npoAykTax.5.2 门pegenbi o6HapyxeHng,4yBctBntenbHoctb n ontuManbhbie quana3oHbi onpegeneHng 3aBncAt otMogen aToMHo-a6cop6MoHHoro cneKTpoMeTpa(cneKTpoOToMeTpa).OCHOBHble XapakTepcTK cnekTpoMeTpa:5.2.1 naMna c nonbiM KaTogoM Ha ene3o;5.2.2 AnHa BonHb-248,3 HM;5.2.3 roploee BeectBo-aetneH(BbIcoKO CTOTbl);5.2.4 oxnchntenb-Bo3Ayx(n3 nnHnn noga4n cxatoro Bo3gyxa,na6opatopHoro komnpeccopa nnn6annoHa ckatoro Bo3Ayxa-Bce AonHO bITb 4CTbIM cyXM);5.2.5 Tun nnaMeH-oKncnTenbHoe;5.2.6 Take MoryT 6bITb cnonb3oBaHbi cnegyiowe nH:248,8 HM-OTHocTenbHa 4yBcTBnTenbHOcTb 2;271,9 HM-oTHocntenbHa 4yBctBntenbHOCtb 4;302,1 HM-OTHOctenbHa 4yBcTBTenbHOCtb 5;252,7 HM-oTHoctenbHa 4yBcTBnTenbHOCtb 6;372,0 HM-OTHocTenbHa 4yBCTBTenbHOCTb 10.5.3 MeToA npeAHa3HayeH Ang yrnem c KoHyeHTpauMAMM pactBopnMoro B kucnoTe xene3a0,0030%0,050%.Ana yrnei c 6onee Bbicokoi koHyeHtpayuei xene3a ucnonb3yiot 6onbwee pa36aBne-He npoobl nM MeHbwne annKBoTbl.5.4 Heo6xognmo yAoctoBeputbcA,4to B Matpnue npo6bi HeT BMewatenbctB Apyrnx meTannoB.2)AokyMeHTbI AOcTyTHbi B HayoHanbHoM MHCTnTyTe cTaHAapToB n TexHonorw CWA(The National Institute ofStandards and Technology,NIST,100 Bureau Dr.,Stop 1070,Gaithersburg,MD 20899-1070,http:/www.nist.gov.2FOCT 33580-20155.5 Bo n36exahne nonyyehna own6o4hbix pe3ynbtatoB Heo6xogumo chegutb,4to6bi hn oAuH xene3-Hbi HctpyMeHt He KoHTaktupoBan hn cogHon3 npo6 unnpactBopoM,cnonb3yeMbiMnB npoyecce ncnbita-Hu.Aonyckaetca npumeHAtb tonbko ctekno,kepamnky unu nnactnk.6 Annaparypa6.1 AToMHo-a6cop6noHHbi cnekTpoMeTp(cneKTpopoToMeTp),cocToAwn n3 ncTo4HnKa cBeTa,n3ny4alouero nnheiHbi cnetp 3nemeHta(cM.5.2.1),yctpoictBa n pacnbineHng npo6b(06bI4Ho nnaMg),cpeActBa(npucnoco6neHne,yctponctBo)n3onAnn nuHnn nornow(eHnA(MoHoxpoMatop nnu unLtp u pery-nnpyeMa u(enb cM.5.2.2 n5.2.6),a Takke poToanektpn4eckoro getekTopa cBA3aHHoro c HM 3neKTpoH-Horo ycnTeng 3MepTenbHoro o6opyAoBaHA.6.2 Hn3kne na6opaTopHble cTakaHbi pp中Ha BMeCTnMOCTbio 400 Mn n3 6opocnnnKatHoro cteknanM aHanor4Hble.6.3 pagypoBaHHbi nHAp BMecTMOCTb 100 Mn.6.4 nbtpoBanbHa Kon6a c 6oKoBo Tpy6Ko BMecTuMOCTb 250 Mn.6.5 BopoHka BoxHepa pa3Mepa D BHyTpeHHMM AMaMeTpoM 71 MM.6.6 ByMaxHbi ntp BatMaH N 3 naMeTpoM 7,0 cm n aHanornyHbi.6.7 Kon6b BMeCTMOCTb 50,100,250,500 n 1000 Mn.6.8 uneTkn BMeCTMOCTbo 1,2,5,10,25 n 100 Mn.6.9 CTO 325 Mew.6.10 AHannTn4eckne Becb c TO4HOCTbi B3BeWnBaHnA 0,0001 r.6.11 3nekTpecka nnutka.p u M e 4 a H n e 1-Bce n3MepnTentHoe o6opyAoBaHne gOnxHO cOoTBeTCTBOBatb nnn npeBbiwatL TPe6oBa-HnA ny6nnKaynn NIST Circular 602.MepHoe o6opyoBaHne,cooTBeTcTByoee aTnM TeXHnecknM Tpe6oBaHnAM,06bIHHOo6o3HaaeTcA KaK Knacc A.TaKe cM.TeXHn4ecKne Tpe6oBaH ASTM E 287 n ASTM E 288.7 PeaKTMBbl7.1 YncToTa peaktBoB.Ang Bcex ncnbiTaHnn ncnonb3yioT peaKTnBbi kBannnkaynn 4.A.a.(reagentgrade),To ectb Bce peaKtnBbi gOnHbi cOOTBeTCTBOBatb TeXHnecKnM Tpe6oBaHnAM KoMTeTa no aHann3ypeaKTBoB AMepnKaHckoro xnMM4eckoro o6ecTBa(Committee on Analytical Reagents of the AmericanChemical Society),rAe Takne Tpe6oBaHng MoKHo Hatn.MoryT 6bITb ncnonb3oBaHbI peaKTuBbi Apyrnx MapoKnpn ycnoBnn npeABaputenbHoro nogTBepxgeHng gOcTaTo4HO BbicoKon cTeneHn 4ncTOTbi,coxpaHAowenToHOCTb onpeeneH.7.2 YncTota BoAbi.Boga gonxHa cooTBeTcTBOBatb texHn4ecknM Tpe6oBaHnAM,ycTaHOBneHHbIM Anna6opaTopHo BoAbi Tna ll no ASTM D 1193.7.3 CTaHAapTHbi pactBop xene3a Ne I:nonHoctbio pactBopAoT 0,1000 r xene3Ho npoBonokn C.P.B20 mn koHLeHtpnpoBahhon congho kncnotbi kBannpnkalnn 4.A.a.n 50 mn BoAbi.OTctanBaot B teyeHneHo4n.AkkypatHo nepeHocAt pactBop B MepHyio koN6y BMectuMOctbio 1 nu gonuBaiot go metkn Bogoi.Ta-TenbHo nepeMewnBaoT.NonyuaoT pacTBop,cogepaw 0,1 Mr ene3a Ha 1 Mn.7.4 CTaHAapthbi pactBop xene3a Ne ll:nunetKou nepeHocAt 100 Mn cTaHAaptHoro pactBopa xene3aNe Is mepHyio kon6y BMectuMoctbio 1 n.AonuBaiot go Metkn Bogoi.TwatenbHo nepemewnBaiot.NonyalotpacTBop,cogepa 0,01 Mr xenesa Ha 1 Mn.p n M e 4 a H n e 2-AonyckaeTc ncnonb3oBaHne pacTBopoB xene3a,KoTopble MoHo npno6pecTn B Mara3n-Hax XnMn4ecKnx Be(ecTB n peaKTnBoB.门pn 3TOM He06xognMO 06ecne4NTb cOOTBeTCTBMe TaKnX peaKTBOB yCTaHOBNeH-HbIM TpeoBaHMAM.8 Mepbi npeAocTopOKHOCT8.1 CyecTByeT Heckonbko noTeHyanbHbix onacHoctei,cBA3aHHbix c npoBeAeHneM HacTogueroucnbiTaHnA.Hactogw ctaHgapt He npeteHAyet ha nonHoty onncaHng Bcex Mep 6e3onacHocT,ecnn Tako-Bble MeoTc,cB3aHhbix cero cnonb3oBaHeM.oNb3oBaTenb cTaHgapta HeceToTBeTCTBeHHOCTb 3a o6ec-ne4eHe cOoTBeTCTByoLX Mep 6e3onacHOCT OXpaHbI 3AOpoBbA n onpegenget enecooopa3HOCTbnpuMeHeH 3akoHogatenbHbix orpaHn4eHn nepeg ero cnonb3oBaHeM.8.1.1 pu pa6ote c conAHo kncnoto Heo6xognMo ncnonb3oBatb cpeActBa nHAuBngyanbHo 3awn-tbi,BKnio4ag pe3nHoBble nepyatkn,na6opatophbi 中aptyK u 3anTHble o4kn.pu pa6ote c xnMn4ecknMn3