ASTM_D_7061_-_19e1.pdf

Designation:D7061191Standard Test Method forMeasuring n-Heptane Induced Phase Separation ofAsphaltene-Containing Heavy Fuel Oils as SeparabilityNumber by an Optical Scanning Device1This standard is issued under the fixed designation D7061;the number immediately following the designation indicates the year oforiginal adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.Asuperscript epsilon()indicates an editorial change since the last revision or reapproval.1NOTEEditorially updated Eq 2 and Eq 3 in April 2020.1.Scope*1.1 This test method covers the quantitative measurement,either in the laboratory or in the field,of how easily asphaltene-containing heavy fuel oils diluted in toluene phase separateupon addition of heptane.This is measured as a separabilitynumber(%)by the use of an optical scanning device.1.2 The test method is limited to asphaltene-containingheavy fuel oils.ASTM specification fuels that generally fallwithin the scope of this test method are Specification D396,Grade Nos.4,5,and 6,Specification D975,Grade No.4-D,and Specification D2880,Grade Nos.3-GT and 4-GT.Refineryfractions from which such blended fuels are made also fallwithin the scope of this test method.1.3 The values stated in SI units are to be regarded asstandard.No other units of measurement are included in thisstandard.1.4 This standard does not purport to address all of thesafety concerns,if any,associated with its use.It is theresponsibility of the user of this standard to establish appro-priate safety,health,and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade(TBT)Committee.2.Referenced Documents2.1 ASTM Standards:2D396 Specification for Fuel OilsD975 Specification for Diesel FuelD2880 Specification for Gas Turbine Fuel OilsD4057 Practice for Manual Sampling of Petroleum andPetroleum ProductsD4177 Practice for Automatic Sampling of Petroleum andPetroleum Products3.Terminology3.1 Definitions:3.1.1 asphaltenes,n(rarely used in the singular),in petro-leum technology,represent an oil fraction that is soluble in aspecified aromatic solvent but separates upon addition of anexcess of a specified paraffinic solvent.3.1.1.1 DiscussionIn this test method,the aromatic sol-vent is toluene and the paraffinic solvent is heptane.3.1.2 compatibility,nof crude oils or of heavy fuel oils,the ability of two or more crude oils or fuel oils to blendtogether within certain concentration ranges without evidenceof separation,such as the formation of multiple phases.3.1.2.1 DiscussionIncompatible heavy fuel oils or crudeoils,when mixed or blended,result in the flocculation orprecipitation of asphaltenes.Some oils may be compatiblewithin certain concentration ranges in specific mixtures,butincompatible outside those ranges.3.1.3 flocculation,nof asphaltenes from crude oils orheavy fuel oils,the aggregation of colloidally dispersed as-phaltenes into visibly larger masses that may or may not settle.1This test method is under the jurisdiction of ASTM Committee D02 onPetroleum Products,Liquid Fuels,and Lubricants and is the direct responsibility ofSubcommittee D02.14 on Stability,Cleanliness and Compatibility of Liquid Fuels.Current edition approved Dec.1,2019.Published January 2020.Originallyapproved in 2004.Last previous edition approved in 2017 as D7061 17.DOI:10.1520/D7061-19E01.2For referenced ASTM standards,visit the ASTM website,www.astm.org,orcontact ASTM Customer Service at serviceastm.org.For Annual Book of ASTMStandards volume information,refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes section appears at the end of this standardCopyright ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959.United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards,Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade(TBT)Committee.3.1.4 peptization,nof asphaltenes in crude oils or heavyfuel oils,the dispersion of asphaltenes to produce a colloidaldispersion.3.1.5 stability reserve,nof crude oils,heavy fuel oils,andresidual streams containing asphaltenes,the property of an oilto maintain asphaltenes in a peptized(colloidally dispersed)state and prevent flocculation of the asphaltenes.3.1.5.1 DiscussionAn oil with a low stability reserve islikely to undergo flocculation of asphaltenes when stressed(forexample,extended heated storage)or blended with a range ofother oils.Two oils each wit